Taming Living Carbocations in Catalytic Direct Conjugate Addition of Simple Alkenes to alpha,beta-Enones
文献类型:期刊论文
作者 | Lv, Jian1,2; Zhong, Xingren1; Luo, Sanzhong1,2 |
刊名 | CHEMISTRY-A EUROPEAN JOURNAL
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出版日期 | 2014-07-01 |
卷号 | 20期号:27页码:8293-8296 |
关键词 | Alkenes Anionic Ligands Iron Vinylation |
ISSN号 | 0947-6539 |
DOI | 10.1002/chem.201402246 |
英文摘要 | A Lewis acid in the presence of an anionic phosphate ligand enables the addition of alkenes to alpha,beta-enones. The ligand facilitates selective beta-proton elimination by suppressing competing pathways, thus leading to vinylation adducts in high yields (up to 99%) for a broad range of substrates. |
语种 | 英语 |
WOS记录号 | WOS:000338019300009 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/50269] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Luo, Sanzhong |
作者单位 | 1.Chinese Acad Sci, BNLMS, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China 2.Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China |
推荐引用方式 GB/T 7714 | Lv, Jian,Zhong, Xingren,Luo, Sanzhong. Taming Living Carbocations in Catalytic Direct Conjugate Addition of Simple Alkenes to alpha,beta-Enones[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(27):8293-8296. |
APA | Lv, Jian,Zhong, Xingren,&Luo, Sanzhong.(2014).Taming Living Carbocations in Catalytic Direct Conjugate Addition of Simple Alkenes to alpha,beta-Enones.CHEMISTRY-A EUROPEAN JOURNAL,20(27),8293-8296. |
MLA | Lv, Jian,et al."Taming Living Carbocations in Catalytic Direct Conjugate Addition of Simple Alkenes to alpha,beta-Enones".CHEMISTRY-A EUROPEAN JOURNAL 20.27(2014):8293-8296. |
入库方式: OAI收割
来源:化学研究所
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