Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19)
文献类型：期刊论文
| 作者 | Zhang, Bin1,2; Zhang, Yan3,4; Chang, Guangcai5; Gao, Zengqiang5; Wang, Dongwei6; Zhu, Daoben1,2 |
| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2014-09-01 |
| 卷号 | 421页码:399-404 |
| 关键词 | Iron Oxalate Hydroxo Oxo Magnetism |
| ISSN号 | 0020-1693 |
| DOI | 10.1016/j.ica.2014.07.001 |
| 英文摘要 | Heterometallic yellow compound Ba-3[Fe(C2O4)(3)](2)(H2O)(12) (1) with mononuclear anion [Fe(C2O4)(3)(3-)] can be transformed to heterometallic red compound Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19) (2) with OH/O bridged tetranuclear anion [Fe4O(OH)(3)(C2O4)(8)(9-)] in the mother liquor. Ba2+ and Fe3+ form three-dimensional networks thorough oxalate anion and H2O molecules in 1 and 2. 1 is a paramagnet and a strong antiferromagnetic interaction as the ground state S = 0 exists in 2. (C) 2014 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000341439300049 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50319]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Bin |
| 作者单位 | 1.Chinese Acad Sci, OSL, BNLMS, CMS, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 3.Peking Univ, Dept Phys, Inst Condensed Matter, Beijing 100871, Peoples R China 4.Peking Univ, Dept Phys, Dept Mat Phys, Beijing 100871, Peoples R China 5.Chinese Acad Sci, BSRF, Inst High Energy Phys, Beijing 100047, Peoples R China 6.Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Bin,Zhang, Yan,Chang, Guangcai,et al. Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19)[J]. INORGANICA CHIMICA ACTA,2014,421:399-404. |
| APA | Zhang, Bin,Zhang, Yan,Chang, Guangcai,Gao, Zengqiang,Wang, Dongwei,&Zhu, Daoben.(2014).Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19).INORGANICA CHIMICA ACTA,421,399-404. |
| MLA | Zhang, Bin,et al."Synthesis, crystal structures and characterization of two heterometallic compounds: Ba-3[Fe(C2O4)(3)](2)(H2O)(12) and Ba-4.5[Fe4O(OH)(3)(C2O4)(8)](H2O)(19)".INORGANICA CHIMICA ACTA 421(2014):399-404. |
入库方式： OAI收割
来源：化学研究所
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