Reversible Multichannel Detection of Cu2+ Using an Electropolymerized Film
文献类型：期刊论文
| 作者 | Gong, Zhong-Liang; Cui, Bin-Bin; Yang, Wen-Wen; Yao, Jiannian; Zhong, Yu-Wu |
| 刊名 | ELECTROCHIMICA ACTA
 |
| 出版日期 | 2014-06-01 |
| 卷号 | 130页码:748-753 |
| 关键词 | Cu Sensor Electropolymerization Cyclometalated Ruthenium Vinyl-substituted Complexes Dipicolylamine |
| ISSN号 | 0013-4686 |
| DOI | 10.1016/j.electacta.2014.03.096 |
| 英文摘要 | The reductive co-electropolymerization of vinyl-substituted ruthenium complexes 2(PF6) and 3(PF6)(2) at ITO glass electrodes have afforded adherent metallopolymeric films, where complex 2(PF6) contains a dipicolylamine (DPA) unit as the ion recognition site and 3(PF6)(2) is a ruthenium monomer without DPA. The resulting thin films can selectively detect Cu2+ at the solid-liquid interface on the basis of color, absorption, and electrochemical changes. By using EDTA to remove the incorporated Cu2+, the polymeric film can repeatedly detect Cu2+ with good reversibility and film stability, as supported by XPS and TEM analyses. (C) 2014 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000336880700097 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50337]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhong, Yu-Wu |
| 作者单位 | Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gong, Zhong-Liang,Cui, Bin-Bin,Yang, Wen-Wen,et al. Reversible Multichannel Detection of Cu2+ Using an Electropolymerized Film[J]. ELECTROCHIMICA ACTA,2014,130:748-753. |
| APA | Gong, Zhong-Liang,Cui, Bin-Bin,Yang, Wen-Wen,Yao, Jiannian,&Zhong, Yu-Wu.(2014).Reversible Multichannel Detection of Cu2+ Using an Electropolymerized Film.ELECTROCHIMICA ACTA,130,748-753. |
| MLA | Gong, Zhong-Liang,et al."Reversible Multichannel Detection of Cu2+ Using an Electropolymerized Film".ELECTROCHIMICA ACTA 130(2014):748-753. |
入库方式： OAI收割
来源：化学研究所
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