Dicyanovinyl-functionalized fluorescent hyperbranched conjugated polymer nanoparticles for sensitive naked-eye cyanide ion detection
文献类型：期刊论文
| 作者 | Li, Haibo1,2; Wu, Xiaofu1; Xu, Yuxiang1,2; Tong, Hui1; Wang, Lixiang1 |
| 刊名 | POLYMER CHEMISTRY
 |
| 出版日期 | 2014-10-21 |
| 卷号 | 5期号:20页码:5949-5956 |
| ISSN号 | 1759-9954 |
| DOI | 10.1039/c4py00592a |
| 英文摘要 | A selective and sensitive fluorescent nanoprobe based on hyperbranched conjugated polymer nanoparticles (HBCPN-DCV) for cyanide detection was developed. HBCPN-DCV was readily prepared by Suzuki coupling polymerization in a mini-emulsion, followed by post-functionalization of numerous terminal aldehyde groups into cyanide-responsive dicyanovinyl fluorophores on the particle surface. An efficient Forster resonance energy transfer from the HBCPN core to the peripheral dicyanovinyl dyes was achieved in HBCPN-DCV. Taking advantage of the amplified energy transfer, the fluorescent turn-off cyanide detection mode of its model compound (M-DCV) could be transformed into the turn-on and ratiometric detection mode of HBCPN-DCV, with a limit of detection down to 0.2 mu M. Meanwhile, clear fluorescent colour change at a cyanide concentration as low as 2 mu M could be observed by the naked eye. In addition, compared to M-DCV, HBCPN-DCV exhibits higher sensitivity and wider linear region. |
| 语种 | 英语 |
| WOS记录号 | WOS:000342479100011 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50349]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tong, Hui |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Haibo,Wu, Xiaofu,Xu, Yuxiang,et al. Dicyanovinyl-functionalized fluorescent hyperbranched conjugated polymer nanoparticles for sensitive naked-eye cyanide ion detection[J]. POLYMER CHEMISTRY,2014,5(20):5949-5956. |
| APA | Li, Haibo,Wu, Xiaofu,Xu, Yuxiang,Tong, Hui,&Wang, Lixiang.(2014).Dicyanovinyl-functionalized fluorescent hyperbranched conjugated polymer nanoparticles for sensitive naked-eye cyanide ion detection.POLYMER CHEMISTRY,5(20),5949-5956. |
| MLA | Li, Haibo,et al."Dicyanovinyl-functionalized fluorescent hyperbranched conjugated polymer nanoparticles for sensitive naked-eye cyanide ion detection".POLYMER CHEMISTRY 5.20(2014):5949-5956. |
入库方式： OAI收割
来源：化学研究所
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