中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
In situ synthesis of binded, thick and porous carbon nanoparticle dye sensitized solar cell counter electrode with nickel gel as catalyst source

文献类型:期刊论文

作者Zeng, Wei1,2; Fang, Guojia1; Han, Tianyang1; Li, Borui1; Liu, Nishuang1; Zhao, Dongshan1; Liu, Zhiqiang2; Wang, Dianyuan2; Zhao, Xingzhong1; Zou, Dechun3
刊名JOURNAL OF POWER SOURCES
出版日期2014
卷号245页码:456-462
关键词Nickel Gel Titanium Dioxide Flame Synthesis Carbon Nanoparticle Counter Electrode Dye Sensitized Solar Cell Mass Transport
ISSN号0378-7753
DOI10.1016/j.jpowsour.2013.06.157
英文摘要A TiO2-embedded NiCl2 gel is prepared and used as growth catalyst to in situ synthesize binded, thick and porous carbon nanoparticles (CNPs) on Ti foil substrate with a simple flame synthesis method for dye sensitized solar cell (DSSC) counter electrode (CE) applications. The viscous gel catalyst can hold sufficient NiCl2 coated on substrate to make CNP layer thick. The embedded TiO2 can effectively separate the abundant NiCl2 components to active the Ni catalyst for CNP growth and then make CNP layer become porous. In addition, the TiO2 components can bind the porous CNP products to make them conductive. With an optimized TiO2 fraction, the CE shows high catalytic ability and electrical conductivity. By applying this CNP CE for DSSC, a photovoltaic conversion efficiency of 6.6% is achieved, which exceeds 6.5% of a reference cell using costly platinum as CE. Furthermore, the CNP structure is demonstrated beneficial to carrier transport by a mass transfer model. This easy and effective preparation method may have a potential application in general nanomaterial preparation. (C) 2013 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000325234500057
出版者ELSEVIER SCIENCE BV
源URL[http://ir.iccas.ac.cn/handle/121111/50393]  
专题中国科学院化学研究所
通讯作者Fang, Guojia
作者单位1.Wuhan Univ, Sch Phys & Technol, Minist Educ China, Key Lab Artificial Micro & Nanostruct, Wuhan 430072, Peoples R China
2.Jiujiang Univ, Coll Sci, Jiujiang 332005, Peoples R China
3.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Key Lab Polymer Chem & Phys,Minist Educ, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Zeng, Wei,Fang, Guojia,Han, Tianyang,et al. In situ synthesis of binded, thick and porous carbon nanoparticle dye sensitized solar cell counter electrode with nickel gel as catalyst source[J]. JOURNAL OF POWER SOURCES,2014,245:456-462.
APA Zeng, Wei.,Fang, Guojia.,Han, Tianyang.,Li, Borui.,Liu, Nishuang.,...&Zou, Dechun.(2014).In situ synthesis of binded, thick and porous carbon nanoparticle dye sensitized solar cell counter electrode with nickel gel as catalyst source.JOURNAL OF POWER SOURCES,245,456-462.
MLA Zeng, Wei,et al."In situ synthesis of binded, thick and porous carbon nanoparticle dye sensitized solar cell counter electrode with nickel gel as catalyst source".JOURNAL OF POWER SOURCES 245(2014):456-462.

入库方式: OAI收割

来源:化学研究所

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