Biphenyl-Bridged 6-(1-Aryliminoethyl)-2-iminopyridylcobalt Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior
文献类型：期刊论文
| 作者 | Xing, Qifeng1; Zhao, Tong1; Du, Shizhen1; Yang, Wenhong1; Liang, Tongling1; Redshaw, Carl2; Sun, Wen-Hua1
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| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2014-03-24 |
| 卷号 | 33期号:6页码:1382-1388 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/om4010884 |
| 英文摘要 | A series of biphenyl-bridged 6-(1-aryliminoethyl)-2-iminopyridine derivatives reacted with cobalt dichloride in dichloromethane/ethanol to afford the corresponding binuclear cobalt complexes. The cobalt complexes were characterized by FT-IR spectroscopy and elemental analysis, and the structure of a representative complex was confirmed by single-crystal X-ray diffraction. Upon activation with either MAO or MMAO, these cobalt complexes performed with high activities of up to 1.2 x 10(7) g (mol of Co)(-1) h(-1) in ethylene polymerization, which represents one of the most active cobalt-based catalytic systems in ethylene reactivity. These biphenyl-bridged bis(imino)pyridylcobalt precatalysts exhibited higher activities than did their mononuclear bis(imino)pyridylcobalt precatalyst counterparts, and more importantly, the binuclear precatalysts revealed a better thermal stability and longer lifetimes. The polyethylenes obtained were characterized by GPC, DSC, and high-temperature NMR spectroscopy and mostly possessed unimodal and highly linear features. |
| 语种 | 英语 |
| WOS记录号 | WOS:000333478400009 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50403]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Redshaw, Carl |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England |
| 推荐引用方式 GB/T 7714 | Xing, Qifeng,Zhao, Tong,Du, Shizhen,et al. Biphenyl-Bridged 6-(1-Aryliminoethyl)-2-iminopyridylcobalt Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior[J]. ORGANOMETALLICS,2014,33(6):1382-1388. |
| APA | Xing, Qifeng.,Zhao, Tong.,Du, Shizhen.,Yang, Wenhong.,Liang, Tongling.,...&Sun, Wen-Hua.(2014).Biphenyl-Bridged 6-(1-Aryliminoethyl)-2-iminopyridylcobalt Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior.ORGANOMETALLICS,33(6),1382-1388. |
| MLA | Xing, Qifeng,et al."Biphenyl-Bridged 6-(1-Aryliminoethyl)-2-iminopyridylcobalt Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior".ORGANOMETALLICS 33.6(2014):1382-1388. |
入库方式： OAI收割
来源：化学研究所
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