Pt nanoparticles over TiO2-ZrO2 mixed oxide as multifunctional catalysts for an integrated conversion of furfural to 1,4-butanediol
文献类型：期刊论文
| 作者 | Li, Fengbo; Lu, Tao; Chen, Bingfeng; Huang, Zhijun; Yuan, Guoqing |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2014-05-20 |
| 卷号 | 478页码:252-258 |
| 关键词 | Biomass Conversion Heterogeneous Catalysis Integrated Process Furfural Bdo |
| ISSN号 | 0926-860X |
| DOI | 10.1016/j.apcata.2014.04.012 |
| 英文摘要 | 1,4-butanediol (BDO) is an important commodity chemical for manufacturing many basic chemicals and valuable polymers. Its current manufacturing processes are exclusively based on feedstocks derived from oil and natural gas. The biomass-to-BDO chemical transformation is via furfural, a key platform molecule from glucose and xylose. The integrated conversion involves two sequent reaction steps: selective oxidation of furfural to furanones and hydrogenation of the mixture of furanones to BDO. Platinum nanoparticles supported over TiO2-ZrO2 perform well for both oxidation and hydrogenation steps and the total yield of BDO reaches 85.2%. The chemical composition and crystallinity of the mixed oxide support significantly affect the catalytic performance. The best catalyst is platinum supported over TiO2-ZrO2 mixed oxide (Ti/Zr, 1:1) calcined at 823 K, which also exhibits good recoverability and recyclability in the five-run test. (C) 2014 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000336878800030 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50537]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Fengbo |
| 作者单位 | Chinese Acad Sci, Inst Chem, Key Lab Green Printing, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Fengbo,Lu, Tao,Chen, Bingfeng,et al. Pt nanoparticles over TiO2-ZrO2 mixed oxide as multifunctional catalysts for an integrated conversion of furfural to 1,4-butanediol[J]. APPLIED CATALYSIS A-GENERAL,2014,478:252-258. |
| APA | Li, Fengbo,Lu, Tao,Chen, Bingfeng,Huang, Zhijun,&Yuan, Guoqing.(2014).Pt nanoparticles over TiO2-ZrO2 mixed oxide as multifunctional catalysts for an integrated conversion of furfural to 1,4-butanediol.APPLIED CATALYSIS A-GENERAL,478,252-258. |
| MLA | Li, Fengbo,et al."Pt nanoparticles over TiO2-ZrO2 mixed oxide as multifunctional catalysts for an integrated conversion of furfural to 1,4-butanediol".APPLIED CATALYSIS A-GENERAL 478(2014):252-258. |
入库方式： OAI收割
来源：化学研究所
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