Effects of Fullerene Bisadduct Regioisomers on Photovoltaic Performance
文献类型:期刊论文
作者 | Meng, Xiangyue1,4; Zhao, Guangyao2,4; Xu, Qi3; Tan, Zhan'ao3; Zhang, Zhuxia1; Jiang, Li1; Shu, Chunying1; Wang, Chunru1; Li, Yongfang2 |
刊名 | ADVANCED FUNCTIONAL MATERIALS
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出版日期 | 2014 |
卷号 | 24期号:1页码:158-163 |
关键词 | Polymer Solar Cells Electron Acceptors Bisadduct Fullerene Regioisomers |
ISSN号 | 1616-301X |
DOI | 10.1002/adfm.201301411 |
英文摘要 | Fullerene bisadducts have emerged as promising electron-accepting materials because of their ability to increase the open-circuit voltage (V-OC) of polymer solar cells (PSCs) due to their relatively high lowest unoccupied molecular orbital (LUMO) energy levels. It should be noted that the as-prepared fullerene bisadducts are in fact a mixture of isomers. Here, the effects of fullerene bisadduct regioisomers on photovoltaic performance are examined. The trans-2, trans-3, trans-4, and e isomers of dihydronaphthyl-based [60]fullerene bisadduct (NCBA) are isolated and used as acceptors for P3HT-based PSCs. The four NCBA isomers exhibit different absorption spectra, electrochemical properties, and electron mobilities, leading to varying PCE values of 5.8, 6.3, 5.6, and 5.5%, respectively, which are higher than that based on an NCBA mixture (5.3%), suggesting the necessity to use the individual fullerene bisadduct isomer for high-performance PSCs. |
语种 | 英语 |
WOS记录号 | WOS:000330589300017 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/50549] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Meng, Xiangyue |
作者单位 | 1.Chinese Acad Sci, Key Lab Mol Nanostruct & Nanotechnol, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China 3.North China Elect Power Univ, State Key Lab Alternate Elect Power Syst Renewabl, New & Renewable Energy Beijing Key Lab, Beijing 102206, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Meng, Xiangyue,Zhao, Guangyao,Xu, Qi,et al. Effects of Fullerene Bisadduct Regioisomers on Photovoltaic Performance[J]. ADVANCED FUNCTIONAL MATERIALS,2014,24(1):158-163. |
APA | Meng, Xiangyue.,Zhao, Guangyao.,Xu, Qi.,Tan, Zhan'ao.,Zhang, Zhuxia.,...&Li, Yongfang.(2014).Effects of Fullerene Bisadduct Regioisomers on Photovoltaic Performance.ADVANCED FUNCTIONAL MATERIALS,24(1),158-163. |
MLA | Meng, Xiangyue,et al."Effects of Fullerene Bisadduct Regioisomers on Photovoltaic Performance".ADVANCED FUNCTIONAL MATERIALS 24.1(2014):158-163. |
入库方式: OAI收割
来源:化学研究所
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