Lamellae break induced formation of shish-kebab during hot stretching of ultra-high molecular weight polyethylene precursor fibers investigated by in situ small angle X-ray scattering
文献类型：期刊论文
| 作者 | Tian, Yu1; Zhu, Caizhen1,2,3; Gong, Jinghua1; Yang, Shenglin1; Ma, Jinghong1; Xu, Jian1,3 |
| 刊名 | POLYMER
 |
| 出版日期 | 2014-08-05 |
| 卷号 | 55期号:16页码:4299-4306 |
| 关键词 | Ultra-high Molecular Weight Polyethylene Fiber In Situ Small-angle X-ray scatterIng Measurement Microstructure Evolution |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2014.06.056 |
| 英文摘要 | The extracted low-oriented ultra-high molecular weight polyethylene precursor fibers were stretched at the temperature of 80 degrees C. In situ small-angle X-ray scattering (SAXS) measurement using synchrotron radiation was applied to study the microstructure evolutions of fibers including the deformation and break of lamellae, the diminishing of microvoids, and the formation of shish-kebab. It was found that hot stretching could induce different kinds of SAXS patterns: two-point pattern indicating the stacking lamellae, X-shaped pattern indicating the tilted state of lamellae, the changing of streak pattern indicating the evolution of microvoids and shish structures respectively. During later stage of stretching, the shish structures along the fiber axis became remarkable to develop the final shish-kebab structures accompanied by the break-reorganization of original lamellae. The results also reveal the close relationship between macroscopic deformation and microstructural evolution that the macroscopic external stress loaded on internal microstructures can effectively promote the transformation from chain-folded lamellae to chain-extended crystals. (C) 2014 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000340812300112 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50553]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhu, Caizhen |
| 作者单位 | 1.Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China 2.Shenzhen Univ, Coll Chem & Chem Engn, Shenzhen Key Lab Funct Polymers, Shenzhen 518060, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tian, Yu,Zhu, Caizhen,Gong, Jinghua,et al. Lamellae break induced formation of shish-kebab during hot stretching of ultra-high molecular weight polyethylene precursor fibers investigated by in situ small angle X-ray scattering[J]. POLYMER,2014,55(16):4299-4306. |
| APA | Tian, Yu,Zhu, Caizhen,Gong, Jinghua,Yang, Shenglin,Ma, Jinghong,&Xu, Jian.(2014).Lamellae break induced formation of shish-kebab during hot stretching of ultra-high molecular weight polyethylene precursor fibers investigated by in situ small angle X-ray scattering.POLYMER,55(16),4299-4306. |
| MLA | Tian, Yu,et al."Lamellae break induced formation of shish-kebab during hot stretching of ultra-high molecular weight polyethylene precursor fibers investigated by in situ small angle X-ray scattering".POLYMER 55.16(2014):4299-4306. |
入库方式： OAI收割
来源：化学研究所
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