Effects of fluorination on the properties of thieno [3,2-b]thiophene-bridged donor-pi-acceptor polymer semiconductors
文献类型：期刊论文
| 作者 | Wang, Xiaochen1,2; Zhang, Zhi-Guo2; Luo, Hao2; Chen, Song3; Yu, Shunquan1; Wang, Haiqiao1; Li, Xiaoyu1; Yu, Gui2; Li, Yongfang2 |
| 刊名 | POLYMER CHEMISTRY
 |
| 出版日期 | 2014 |
| 卷号 | 5期号:2页码:502-511 |
| ISSN号 | 1759-9954 |
| DOI | 10.1039/c3py00940h |
| 英文摘要 | Thieno[3,2-b]thiophene-bridged polymer semiconductors, P(BDT-TT-HBT) and P(BDT-TT-FBT), combining a benzo[1,2-b:4,5-b']dithiophene donor unit and a benzothiadiazole or fluorinated benzothiadiazole acceptor unit, respectively, were designed and synthesized. The introduction of fluorine substituents remarkably influenced the molecular architecture, optical, electrochemical, and morphological properties of the polymers, as well as the optoelectronic performance of the devices made from these materials. The introduction of fluorine substituents on the benzothiadiazole unit not only down-shifted the HOMO energy level of the organic semiconductor but also enhanced the intra- and intermolecular interactions of the resulting conjugated polymer. As a result, the open-circuit voltage and mobility of corresponding devices based on the fluorinated polymer were enhanced markedly. Power conversion efficiencies of the polymer solar cells based on P(BDT-TT-HBT) and P(BDT-TT-FBT) reached 4.37% and 3.56%, with open circuit voltages of 0.72 and 0.81 V, respectively. The fluorinated polymer exhibited much higher mobilities (4.1 to 6.3 times) than the non-fluorinated polymer, reaching 0.017 cm(2) V-1 s(-1). |
| 语种 | 英语 |
| WOS记录号 | WOS:000328647200030 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50585]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Haiqiao |
| 作者单位 | 1.Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Key Lab Carbon Fiber & Funct Polymers, Minist Educ, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China 3.China Text Acad, Beijing 100025, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xiaochen,Zhang, Zhi-Guo,Luo, Hao,et al. Effects of fluorination on the properties of thieno [3,2-b]thiophene-bridged donor-pi-acceptor polymer semiconductors[J]. POLYMER CHEMISTRY,2014,5(2):502-511. |
| APA | Wang, Xiaochen.,Zhang, Zhi-Guo.,Luo, Hao.,Chen, Song.,Yu, Shunquan.,...&Li, Yongfang.(2014).Effects of fluorination on the properties of thieno [3,2-b]thiophene-bridged donor-pi-acceptor polymer semiconductors.POLYMER CHEMISTRY,5(2),502-511. |
| MLA | Wang, Xiaochen,et al."Effects of fluorination on the properties of thieno [3,2-b]thiophene-bridged donor-pi-acceptor polymer semiconductors".POLYMER CHEMISTRY 5.2(2014):502-511. |
入库方式： OAI收割
来源：化学研究所
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