Synthesis and Reactivity Studies of a Tin(II) Corrole Complex
文献类型：期刊论文
| 作者 | Yun, Lin1; Vazquez-Lima, Hugo3,4; Fang, Huayi1; Yao, Zhengmin1; Geisberger, Georg2; Dietl, Christian2; Ghosh, Abhik3,4; Brothers, Penelope J.2; Fu, Xuefeng1 |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2014-07-07 |
| 卷号 | 53期号:13页码:7047-7054 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/ic501103c |
| 英文摘要 | A series of tris(pentafluorophenyl)corrole (TPFC) tin(IV) and tin(II) complexes were prepared and studied by various characterization techniques including H-1, F-19, and Sn-119 NMR and UV-vis spectroscopy, mass spectrometry, and single-crystal X-ray diffraction. The unusual 4-coordinate, monomeric, divalent tin(II) complex [(TPFC)-Sn-II](-) (2a) showed highly efficient reactivity toward alkenes and alkyl halides via a nudeophilic addition pathway leading to the quantitative formation of alkyl stannyl corrole compounds. DFT calculations confirmed the divalent nature of the tin center in 2a, and an NBO analysis showed about 99.99% Sn lone pair character, of which 83.6% was Sn 5s and 16.35% was Sn 5p character. |
| 语种 | 英语 |
| WOS记录号 | WOS:000338748100073 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50633]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ghosh, Abhik |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Univ Auckland, Sch Chem Sci, Auckland 1142, New Zealand 3.UiT Arctic Univ Norway, Dept Chem, N-9037 Tromso, Norway 4.UiT Arctic Univ Norway, Ctr Theoret & Computat Chem, N-9037 Tromso, Norway |
| 推荐引用方式 GB/T 7714 | Yun, Lin,Vazquez-Lima, Hugo,Fang, Huayi,et al. Synthesis and Reactivity Studies of a Tin(II) Corrole Complex[J]. INORGANIC CHEMISTRY,2014,53(13):7047-7054. |
| APA | Yun, Lin.,Vazquez-Lima, Hugo.,Fang, Huayi.,Yao, Zhengmin.,Geisberger, Georg.,...&Fu, Xuefeng.(2014).Synthesis and Reactivity Studies of a Tin(II) Corrole Complex.INORGANIC CHEMISTRY,53(13),7047-7054. |
| MLA | Yun, Lin,et al."Synthesis and Reactivity Studies of a Tin(II) Corrole Complex".INORGANIC CHEMISTRY 53.13(2014):7047-7054. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。