Syntheses, Structure, and Properties of Mixed Cp-Amidinate Rare-Earth-Metal(III) Complexes
文献类型：期刊论文
| 作者 | Liu, Jun-Feng1,2; Pan, Fu-Xing1,2; Yao, Shuang1; Min, Xue1,2; Cuo, Dongmei3; Sun, Zhong-Ming1 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2014-03-24 |
| 卷号 | 33期号:6页码:1374-1381 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/om400856d |
| 英文摘要 | A family of mixed Cp-amidinate rare-earth-metal(III) complexes [Cp(2)L(1)LnPhCN] (Ln = Y (1), La (2), Sm (3), Eu (4), Gd (5), Tb (6), Dy (7); L-1 = PhC-(NSiMe3)(2)), [Cp(2)L(1)Ln] (Ln = Er (8), Yb (9)), and [Cp(2)L(2)Ln] (Ln = Y (10), Eu (11), Gd (12), Tb (13), Dy (14), Er (15); L-2 = N(t-Bu)C(Ph)N(SiMe3)) were synthesized by treatment of Cp(3)Ln with lithium amidinates. The phase transition has been observed for compounds 5 and 9 at low temperature (200 K). Single-crystal structural analyses reveal that compounds 1, 3, 4, 5b, 6, 7, 9b, and 10-15 contain two staggered Cp rings. In contrast, two eclipsed Cp rings were observed in compounds 2, 5a, 8, and 9a. Moreover, the luminescent properties of complex 6 and magnetic properties of complex 7 were also investigated. |
| 语种 | 英语 |
| WOS记录号 | WOS:000333478400008 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50635]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Zhong-Ming |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Jilin, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Changchun Inst Appl Chem, Changchun 130022, Jilin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Jun-Feng,Pan, Fu-Xing,Yao, Shuang,et al. Syntheses, Structure, and Properties of Mixed Cp-Amidinate Rare-Earth-Metal(III) Complexes[J]. ORGANOMETALLICS,2014,33(6):1374-1381. |
| APA | Liu, Jun-Feng,Pan, Fu-Xing,Yao, Shuang,Min, Xue,Cuo, Dongmei,&Sun, Zhong-Ming.(2014).Syntheses, Structure, and Properties of Mixed Cp-Amidinate Rare-Earth-Metal(III) Complexes.ORGANOMETALLICS,33(6),1374-1381. |
| MLA | Liu, Jun-Feng,et al."Syntheses, Structure, and Properties of Mixed Cp-Amidinate Rare-Earth-Metal(III) Complexes".ORGANOMETALLICS 33.6(2014):1374-1381. |
入库方式： OAI收割
来源：化学研究所
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