(C5H6N)(4)[Be-6(HPO3)(8)]center dot H2O: A low-density open-framework beryllium phosphite with multidirectional 12-ring channels
文献类型：期刊论文
| 作者 | Wang, Guo-Ming1; Li, Jin-Hua1; Zhang, Xiao1; Jiang, Wen-Wen1; Bao, Zhen-Zhen1; Zhao, Xiao-Meng1; Wang, Ying-Xia2; Lin, Jian-Hua2 |
| 刊名 | SOLID STATE SCIENCES
 |
| 出版日期 | 2014-07-01 |
| 卷号 | 33页码:53-57 |
| 关键词 | Beryllium Phosphite Hydrothermal Synthesis Crystal Structure Low Density 12-ring Channel |
| ISSN号 | 1293-2558 |
| DOI | 10.1016/j.solidstatesciences.2014.04.013 |
| 英文摘要 | Employing the common pyridine (=py) solvent as the source of structure-directing agents (SDAs), a novel three-dimensional open-framework beryllium phosphite (Hpy)(4)[Be-6(HPO3)(8)]center dot H2O (1), has been solvothermally synthesized and structurally characterized by IR, elemental analysis, thermogravimetric analysis, powder and single-crystal X-ray diffractions. It crystallizes in the orthorhombic system, space group Pbca (No. 61), a = 20.0034(4) angstrom, b = 20.2188(4) angstrom, c = 20.9731(3) angstrom, V = 8482.5(3) angstrom(3), and Z = 8. The alternating connection of BeO4 tetrahedra and HPO3 pseudopyramids give rise to a (3, 4)-connected network with multidirectional intersecting 12-ring channels. The compound possesses a low densit and a new {4.8.10}{4(2).6.8.10.12}{4(2).6}(3){4(2).8.10(2).12}{4(3).6(2).8} topology. (C) 2014 Elsevier Masson SAS. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000338623500010 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50665]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Guo-Ming |
| 作者单位 | 1.Qingdao Univ, Coll Chem & Chem Engn, Teachers Coll, Qingdao 266071, Shandong, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Guo-Ming,Li, Jin-Hua,Zhang, Xiao,et al. (C5H6N)(4)[Be-6(HPO3)(8)]center dot H2O: A low-density open-framework beryllium phosphite with multidirectional 12-ring channels[J]. SOLID STATE SCIENCES,2014,33:53-57. |
| APA | Wang, Guo-Ming.,Li, Jin-Hua.,Zhang, Xiao.,Jiang, Wen-Wen.,Bao, Zhen-Zhen.,...&Lin, Jian-Hua.(2014).(C5H6N)(4)[Be-6(HPO3)(8)]center dot H2O: A low-density open-framework beryllium phosphite with multidirectional 12-ring channels.SOLID STATE SCIENCES,33,53-57. |
| MLA | Wang, Guo-Ming,et al."(C5H6N)(4)[Be-6(HPO3)(8)]center dot H2O: A low-density open-framework beryllium phosphite with multidirectional 12-ring channels".SOLID STATE SCIENCES 33(2014):53-57. |
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来源：化学研究所
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