Block Copolymer Nanotubular Aggregates Prepared via Direct Self-Assembly in Solution
文献类型:期刊论文
作者 | Wang Lulu1,2; Huang Haiying1; He Tianbai1 |
刊名 | PROGRESS IN CHEMISTRY
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出版日期 | 2014-05-01 |
卷号 | 26期号:5页码:810-819 |
关键词 | Block Copolymer Amphiphilic Self-assembly Micelle Nanotube |
ISSN号 | 1005-281X |
DOI | 10.7536/PC131010 |
英文摘要 | As a kind of novel material, nanotubes with special one-dimensional hollow structure have attracted more and more attention and investigation. Compared with widely studied carbon nanotubes or small amphiphilic molecular nanotubes, block copolymer nanotubes show advantages in dimension scales, functionalization of both inner and outer spaces and structure stability. Recent progress in preparation of nanotubular aggregates via direct self-assembly of block copolymer in selective solvent is reviewed in this paper. According to properties of blocks, block copolymers that can form nanotubes are divided into three categories, including coil-coil block copolymers, rod-coil block copolymers, and pseudo-block copolymers with specific structures. For each category, the preparation procedures, structure characterizations and formation conditions of the nanotubes are introduced. Moreover, mechanisms and regularities of such hollow one-dimensional structure formation are discussed as well. It is proposed that nanotube formation required highly ordered molecular packing and anisotropic intermolecular interactions; thus rod-coil block copolymers are more likely to form polymer nanotube than coil-coil blockcopolymers. Based on these studies, potential applications and possible trends for future research are briefly described finally. |
语种 | 英语 |
WOS记录号 | WOS:000336560200010 |
出版者 | CHINESE ACAD SCIENCES |
源URL | [http://ir.iccas.ac.cn/handle/121111/50669] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Huang Haiying |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Wang Lulu,Huang Haiying,He Tianbai. Block Copolymer Nanotubular Aggregates Prepared via Direct Self-Assembly in Solution[J]. PROGRESS IN CHEMISTRY,2014,26(5):810-819. |
APA | Wang Lulu,Huang Haiying,&He Tianbai.(2014).Block Copolymer Nanotubular Aggregates Prepared via Direct Self-Assembly in Solution.PROGRESS IN CHEMISTRY,26(5),810-819. |
MLA | Wang Lulu,et al."Block Copolymer Nanotubular Aggregates Prepared via Direct Self-Assembly in Solution".PROGRESS IN CHEMISTRY 26.5(2014):810-819. |
入库方式: OAI收割
来源:化学研究所
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