Selectively recognizing organic semiconducting molecules on solid state molecular cages based on ZnOTCPP
文献类型：期刊论文
| 作者 | Liu, Huibiao; Wang, Ke; Zhang, Liang; Qian, Xuemin; Li, Yongjun; Li, Yuliang |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2014 |
| 卷号 | 43期号:2页码:432-438 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c3dt51609a |
| 英文摘要 | In this study, we constructed a novel solid state supramolecular system-the molecular cage ZnOTCPP, based on an inorganic/organic hybrid nanostructure, through the assembly of 5,10,15,20-tetra(3-carboxyphenyl)porphyrin (TCPP) onto the surfaces of ZnO nanorod (NR) arrays. The ZnOTCPP molecular cage exhibited highly selective recognition of 5,10,15,20-tetraphenylporphyrin (TPP) by optical and photoelectrical signals. The ZnOTCPP@TPP exhibited high emission efficiency, with a six-fold increase in the intensity of the emission relative to that of ZnOTCPP after the molecular cage ZnOTCPP captured TPP. The optical, electrical, and optoelectrical properties of the molecular cage ZnOTCPP could be controlled by tuning the interactions between the guest and the host's inorganic or organic moieties. Such a solid state molecular cage opens the door to controlled-delivery applications and provides an attractive platform for studying solid state supramolecular electronics and optoelectronics. |
| 语种 | 英语 |
| WOS记录号 | WOS:000327894400009 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50725]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Huibiao |
| 作者单位 | Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Huibiao,Wang, Ke,Zhang, Liang,et al. Selectively recognizing organic semiconducting molecules on solid state molecular cages based on ZnOTCPP[J]. DALTON TRANSACTIONS,2014,43(2):432-438. |
| APA | Liu, Huibiao,Wang, Ke,Zhang, Liang,Qian, Xuemin,Li, Yongjun,&Li, Yuliang.(2014).Selectively recognizing organic semiconducting molecules on solid state molecular cages based on ZnOTCPP.DALTON TRANSACTIONS,43(2),432-438. |
| MLA | Liu, Huibiao,et al."Selectively recognizing organic semiconducting molecules on solid state molecular cages based on ZnOTCPP".DALTON TRANSACTIONS 43.2(2014):432-438. |
入库方式： OAI收割
来源：化学研究所
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