Primary-Tertiary Diamine/Bronsted Acid Catalyzed alpha-Allylation of Carbonyl Compounds with Allylic Alcohols
文献类型：期刊论文
| 作者 | Cui, Lingyun; Zhang, Long; Luo, Sanzhong; Cheng, Jin-Pei |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2014-08-01 |
| 卷号 | 32期号:8页码:673-677 |
| 关键词 | Organocatalysis Enamine Primary-tertiary Diamine Alpha-allylic Alkylation |
| ISSN号 | 1001-604X |
| DOI | 10.1002/cjoc.201400430 |
| 英文摘要 | A simple and direct alpha-allylic alkylation of unmodified aldehydes with allylic alcohols catalyzed by primary amine/Bronsted acid has been developed. The N,N-dimethylethylenediamine/TfOH was identified as the optimal catalyst to promote this transformation via an enamine process in high yields (up to 88%) and with good diastereoselectivities (up to 9 : 1). |
| 语种 | 英语 |
| WOS记录号 | WOS:000341236900003 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50743]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Luo, Sanzhong |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, Lingyun,Zhang, Long,Luo, Sanzhong,et al. Primary-Tertiary Diamine/Bronsted Acid Catalyzed alpha-Allylation of Carbonyl Compounds with Allylic Alcohols[J]. CHINESE JOURNAL OF CHEMISTRY,2014,32(8):673-677. |
| APA | Cui, Lingyun,Zhang, Long,Luo, Sanzhong,&Cheng, Jin-Pei.(2014).Primary-Tertiary Diamine/Bronsted Acid Catalyzed alpha-Allylation of Carbonyl Compounds with Allylic Alcohols.CHINESE JOURNAL OF CHEMISTRY,32(8),673-677. |
| MLA | Cui, Lingyun,et al."Primary-Tertiary Diamine/Bronsted Acid Catalyzed alpha-Allylation of Carbonyl Compounds with Allylic Alcohols".CHINESE JOURNAL OF CHEMISTRY 32.8(2014):673-677. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。