中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crystallization Features of Normal Alkanes in Confined Geometry

文献类型:期刊论文

作者Su, Yunlan; Liu, Guoming; Xie, Baoquan; Fu, Dongsheng; Wang, Dujin
刊名ACCOUNTS OF CHEMICAL RESEARCH
出版日期2014-01-21
卷号47期号:1页码:192-201
ISSN号0001-4842
DOI10.1021/ar400116c
英文摘要How polymers crystallize can greatly affect their thermal and mechanical properties, which influence the practical applications of these materials. Polymeric materials, such as block copolymers, graft polymers, and polymer blends,. have complex. molecular structures. Due to the multiple hierarchical structures and different size domains In polymer systems, confined hard environments for polymer crystallization exist widely in these materials. The confined geometry Is closely related to both the phase metastability and lifetime of polymer. This affects the phase miscibility, microphase separation, and crystallization behaviors and determines both the performance of polymer materials and how easily these materials can be processed. Furthermore, the size effect of metastable states needs to be clarified in polymers. However, scientists find it difficult to propose a quantitative formula to describe the transition dynamics of metastable states in these complex systems. Normal alkanes [C(n)H(2n+2)n-alkanes] especially linear saturated hydrocarbons, can provide a well-defined model system for studying the complex crystallization behaviors of polymer materials, surfactants, and lipids. Therefore:a deeper investigation of normal alkane phase behavior in confinement will help scientists to understand the crystalline phase transition and ultimate properties of many polymeric materials, especially polyolefins.
语种英语
WOS记录号WOS:000330204400019
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/50753]  
专题中国科学院化学研究所
通讯作者Wang, Dujin
作者单位Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Being Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Su, Yunlan,Liu, Guoming,Xie, Baoquan,et al. Crystallization Features of Normal Alkanes in Confined Geometry[J]. ACCOUNTS OF CHEMICAL RESEARCH,2014,47(1):192-201.
APA Su, Yunlan,Liu, Guoming,Xie, Baoquan,Fu, Dongsheng,&Wang, Dujin.(2014).Crystallization Features of Normal Alkanes in Confined Geometry.ACCOUNTS OF CHEMICAL RESEARCH,47(1),192-201.
MLA Su, Yunlan,et al."Crystallization Features of Normal Alkanes in Confined Geometry".ACCOUNTS OF CHEMICAL RESEARCH 47.1(2014):192-201.

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来源:化学研究所

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