Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containing syn-beta-Hydrogen Atoms
文献类型：期刊论文
| 作者 | Hao, Wei1; Wei, Junnian1; Geng, Weizhi1; Zhang, Wen-Xiong1; Xi, Zhenfeng1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2014-12-22 |
| 卷号 | 53期号:52页码:14533-14537 |
| 关键词 | Elimination Iodine Ligand Effects Palladium Synthetic Methods |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201408341 |
| 英文摘要 | beta-Hydride abstraction is a well-accepted elementary step for catalytic cycles in organometallic chemistry. It is usually anticipated that alkylpalladium halides containing syn-beta-hydrogen atoms will undergo beta-hydride abstraction to afford the Heck-type products. However, this study discloses that the above general knowledge is only conditionally correct. Our experimental results demonstrate that the reductive elimination of alkylhalides from alkylpalladium halides containing syn-beta-hydrogen atoms may surpass the beta-hydride abstraction or even become exclusive in certain cases. |
| 语种 | 英语 |
| WOS记录号 | WOS:000346485800043 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50765]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xi, Zhenfeng |
| 作者单位 | 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hao, Wei,Wei, Junnian,Geng, Weizhi,et al. Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containing syn-beta-Hydrogen Atoms[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(52):14533-14537. |
| APA | Hao, Wei,Wei, Junnian,Geng, Weizhi,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containing syn-beta-Hydrogen Atoms.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(52),14533-14537. |
| MLA | Hao, Wei,et al."Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containing syn-beta-Hydrogen Atoms".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.52(2014):14533-14537. |
入库方式： OAI收割
来源：化学研究所
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