Thermal Methane Activation by La6O10-Cluster Anions
文献类型：期刊论文
| 作者 | Meng, Jing-Heng1,3; Deng, Xiao-Jiao2,3; Li, Zi-Yu1,3; He, Sheng-Gui1; Zheng, Wei-Jun2 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2014-05-05 |
| 卷号 | 20期号:19页码:5580-5583 |
| ISSN号 | 0947-6539 |
| 关键词 | Ch Activation Density Functional Calculations Mass Spectrometry Oxide Cluster Anions Reaction Mechanisms |
| DOI | 10.1002/chem.201400218 |
| 英文摘要 | The first example of a metal oxide cluster anion, La6O10- that can activate methane under ambient conditions is reported. This reaction is facilitated by the oxygen-centered radical (O-) and follows the hydrogen atom transfer mechanism. The La6O10- has a high vertical electron detachment energy (VDE=4.06eV) and a high symmetry (C-4v). |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000335197000010 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50777]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | He, Sheng-Gui |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Meng, Jing-Heng,Deng, Xiao-Jiao,Li, Zi-Yu,et al. Thermal Methane Activation by La6O10-Cluster Anions[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(19):5580-5583. |
| APA | Meng, Jing-Heng,Deng, Xiao-Jiao,Li, Zi-Yu,He, Sheng-Gui,&Zheng, Wei-Jun.(2014).Thermal Methane Activation by La6O10-Cluster Anions.CHEMISTRY-A EUROPEAN JOURNAL,20(19),5580-5583. |
| MLA | Meng, Jing-Heng,et al."Thermal Methane Activation by La6O10-Cluster Anions".CHEMISTRY-A EUROPEAN JOURNAL 20.19(2014):5580-5583. |
入库方式： OAI收割
来源：化学研究所
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