Morphology-controlled self-assembled nanostructures of a porphyrin derivative and their photoelectrochemical properties
文献类型：期刊论文
| 作者 | Cai, Jinhua1,2; Wang, Jingxia2; Tian, Dongliang3; Huang, Jiangen1; Jiang, Lei2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2014 |
| 卷号 | 4期号:8页码:4063-4068 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c3ra46397d |
| 英文摘要 | We have shown that various porphyrin-containing nanostructures can be facilely synthesized by varying the assembly solvent or the temperature in the oil medium, which effectively modulates the evaporation rate and assembly rate of the porphyrin molecules. A dichloromethane solution of 5-(4-(ethylcarboxypropoxy)-phenyl)-10,15,20-tri(naphthyl) porphyrin Zn (CTNP-Zn) was injected into a volume of poor solvent and subsequently mixed with a microinjector. The mixture was cast onto the ITO substrate and then left undisturbed to stabilize the nanostructure under different temperature. After the solvent evaporation, diverse CTNP-Zn based nanostructures, including ring-shaped, honey-comb structured, rice-shaped, hollow spherical, urn-shaped, etc., were successfully assembled depending on the solvent composition or the evaporation temperature. The nanostructures have been characterized by electronic absorption, scanning electron microscopy (SEM) and photoelectric conversion techniques. The internal structures of the nanostructures are described by XRD. It is of great significance for the further extending the applications in optic devices. |
| 语种 | 英语 |
| WOS记录号 | WOS:000329040500051 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50797]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Cai, Jinhua |
| 作者单位 | 1.Jinggangshan Univ, Coll Chem & Chem Engn, Jian 343009, Jiangxi, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 3.Beihang Univ, Key Lab Bioinspired Smart Interfacial Sci & Techn, Minist Educ, Sch Chem & Environm, Beijing 100191, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cai, Jinhua,Wang, Jingxia,Tian, Dongliang,et al. Morphology-controlled self-assembled nanostructures of a porphyrin derivative and their photoelectrochemical properties[J]. RSC ADVANCES,2014,4(8):4063-4068. |
| APA | Cai, Jinhua,Wang, Jingxia,Tian, Dongliang,Huang, Jiangen,&Jiang, Lei.(2014).Morphology-controlled self-assembled nanostructures of a porphyrin derivative and their photoelectrochemical properties.RSC ADVANCES,4(8),4063-4068. |
| MLA | Cai, Jinhua,et al."Morphology-controlled self-assembled nanostructures of a porphyrin derivative and their photoelectrochemical properties".RSC ADVANCES 4.8(2014):4063-4068. |
入库方式： OAI收割
来源：化学研究所
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