Synthesis and hydrogen storage properties of Mg-10.6La-3.5Ni nanoparticles
文献类型：期刊论文
| 作者 | Liu, Tong1; Cao, Yurong1; Qin, Chenggong1; Chou, Wusheng2; Li, Xingguo3 |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2014-01-15 |
| 卷号 | 246页码:277-282 |
| 关键词 | Hydrogen Storage Nanoparticles Kinetics Hydrogen Plasma-metal Reaction |
| ISSN号 | 0378-7753 |
| DOI | 10.1016/j.jpowsour.2013.07.087 |
| 英文摘要 | The Mg-10.6 wt. % La-3.5 wt. % Ni nanoparticles are prepared by hydrogen plasma-metal reaction method. These nanoparticles are made of Mg, LaH3 and a small amount of Mg2Ni. The as-prepared Mg nanoparticles of 180 nm are single crystalline and quasi-spherical in shape, and they change into polycrystalline after activation. LaH3 and Mg2Ni nanoparticles are nearly spherical in shape with the mean particle size of 15 nm, and disperse on the surface of Mg. The Mg-10.6La-3.5Ni nanoparticles can absorb 3.2 wt. % H-2 in less than 15 min at 523 K and accomplish a high hydrogen storage capacity of 6.5 wt. % H-2 in less than 10 min at 673 K, almost reaching the theoretical gravimetric capacity. They can release 4.2 wt. % H-2 in 3 min at 623 K. The synergistic catalytic effect of LaH3 and Mg2Ni nanoparticles, the nanostructure and the low oxide content of Mg nanoparticles promote the hydrogen sorption process with the low hydrogen absorption activation energy of 39.1 kJ mol(-1). (C) 2013 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000326661100037 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50929]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Tong |
| 作者单位 | 1.Beihang Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Aerosp Mat & Performance, Beijing 100191, Peoples R China 2.Beihang Univ, Sch Mech Engn & Automat, Beijing 100191, Peoples R China 3.Peking Univ, Coll Chem & Mol Engn, BNLMS, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Tong,Cao, Yurong,Qin, Chenggong,et al. Synthesis and hydrogen storage properties of Mg-10.6La-3.5Ni nanoparticles[J]. JOURNAL OF POWER SOURCES,2014,246:277-282. |
| APA | Liu, Tong,Cao, Yurong,Qin, Chenggong,Chou, Wusheng,&Li, Xingguo.(2014).Synthesis and hydrogen storage properties of Mg-10.6La-3.5Ni nanoparticles.JOURNAL OF POWER SOURCES,246,277-282. |
| MLA | Liu, Tong,et al."Synthesis and hydrogen storage properties of Mg-10.6La-3.5Ni nanoparticles".JOURNAL OF POWER SOURCES 246(2014):277-282. |
入库方式： OAI收割
来源：化学研究所
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