Reactive compatibilization of high-impact poly(lactic acid)/ethylene copolymer blends catalyzed by N,N-dimethylstearylamine
文献类型：期刊论文
| 作者 | Feng, Yulin1,2; Zhao, Guiyan1; Yin, Jinghua1; Jiang, Wei1 |
| 刊名 | POLYMER INTERNATIONAL
 |
| 出版日期 | 2014-07-01 |
| 卷号 | 63期号:7页码:1263-1269 |
| 关键词 | Poly(Lactic Acid) High Impact Reactive Compatibilization Catalyst |
| ISSN号 | 0959-8103 |
| DOI | 10.1002/pi.4632 |
| 英文摘要 | The inherent brittleness of poly(lactic acid) (PLA) limits its wide application in many fields. Here, high-impact PLA/ethylene-methyl acrylate-glycidyl methacrylate random terpolymer (EMA-GMA) blends were prepared with the addition of a small amount of N,N-dimethylstearylamine (DMSA) catalyst. It was found that the notched impact resistance of various PLA/EMA-GMA blends could be considerably improved by adding DMSA. In particular, the notched Izod impact strength of the blend with 20 wt% EMA-GMA increased from 35.6 to 83.5 kJ m(-2) by adding 0.2 wt% DMSA. Reactive compatibilization between PLA and EMA-GMA with DMSA was studied using Fourier transform infrared spectroscopy. The results indicated that DMSA promoted the reaction between the epoxide group of EMA-GMA and end groups (-OH, -COOH) of PLA. This considerably improved the interfacial adhesion, leading to better wetting of the dispersed phase by the PLA matrix and finer dispersed EMA-GMA particles. Therefore, the significant increase in notched impact strength was attributed to the effective reactive compatibilization promoted by DMSA. (C) 2013 Society of Chemical Industry |
| 语种 | 英语 |
| WOS记录号 | WOS:000337615300019 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50987]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhao, Guiyan |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Kuang Chi Inst Adv Technol, Shenzhen 518057, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng, Yulin,Zhao, Guiyan,Yin, Jinghua,et al. Reactive compatibilization of high-impact poly(lactic acid)/ethylene copolymer blends catalyzed by N,N-dimethylstearylamine[J]. POLYMER INTERNATIONAL,2014,63(7):1263-1269. |
| APA | Feng, Yulin,Zhao, Guiyan,Yin, Jinghua,&Jiang, Wei.(2014).Reactive compatibilization of high-impact poly(lactic acid)/ethylene copolymer blends catalyzed by N,N-dimethylstearylamine.POLYMER INTERNATIONAL,63(7),1263-1269. |
| MLA | Feng, Yulin,et al."Reactive compatibilization of high-impact poly(lactic acid)/ethylene copolymer blends catalyzed by N,N-dimethylstearylamine".POLYMER INTERNATIONAL 63.7(2014):1263-1269. |
入库方式： OAI收割
来源：化学研究所
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