Aminative Umpolung Synthesis of Aryl Vicinal Diamines from Aromatic Aldehydes
文献类型：期刊论文
| 作者 | Liu, Xuliang1,2; Gao, Ang1,2; Ding, Lei1,2; Xu, Juan1,2; Zhao, Baoguo1,2,3 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2014-04-18 |
| 卷号 | 16期号:8页码:2118-2121 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/ol500522d |
| 英文摘要 | In this paper an aminative umpolung synthesis of aryl vicinal diamines from aldehydes and N-Ts imines is described. Electrophilic aromatic aldehydes were smoothly converted into delocalized 2-azaallylanions via condensation with 2,2-diphenylglycine in methanol and subsequent decarboxylation in THF and underwent further reaction with N-Ts imines to give a variety of 1,2-diamine derivatives in good yields with high syn/anti diastereoselectivity. |
| 语种 | 英语 |
| WOS记录号 | WOS:000334823600012 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50989]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhao, Baoguo |
| 作者单位 | 1.Shanghai Normal Univ, Key Lab Resource Chem, Educ Minist, Shanghai 200234, Peoples R China 2.Shanghai Normal Univ, Shanghai Key Lab Rare Earth Funct Mat, Shanghai 200234, Peoples R China 3.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xuliang,Gao, Ang,Ding, Lei,et al. Aminative Umpolung Synthesis of Aryl Vicinal Diamines from Aromatic Aldehydes[J]. ORGANIC LETTERS,2014,16(8):2118-2121. |
| APA | Liu, Xuliang,Gao, Ang,Ding, Lei,Xu, Juan,&Zhao, Baoguo.(2014).Aminative Umpolung Synthesis of Aryl Vicinal Diamines from Aromatic Aldehydes.ORGANIC LETTERS,16(8),2118-2121. |
| MLA | Liu, Xuliang,et al."Aminative Umpolung Synthesis of Aryl Vicinal Diamines from Aromatic Aldehydes".ORGANIC LETTERS 16.8(2014):2118-2121. |
入库方式： OAI收割
来源：化学研究所
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