Biomolecule-Doped PEDOT with Three-Dimensional Nanostructures as Efficient Catalyst for Oxygen Reduction Reaction
文献类型：期刊论文
| 作者 | Guo, Zhaoyan1; Liu, Huan1; Jiang, Congcong1; Zhu, Ying1; Wan, Meixiang2; Dai, Liming3; Jiang, Lei2 |
| 刊名 | SMALL
 |
| 出版日期 | 2014-05-28 |
| 卷号 | 10期号:10页码:2087-2095 |
| 关键词 | Catalysts Hierarchical Structures Nanostructures Oxygen Reduction Reaction Poly(3 4-ethylenedioxythiophene) Self-assembly |
| ISSN号 | 1613-6810 |
| DOI | 10.1002/smll.201303642 |
| 英文摘要 | Metal macro-cyclic compounds have drawn considerable attention as alternative catalysts for oxygen reduction reaction. However, the continuous pyrolysis process usually needed for improving the performance of these compounds require an elevated temperature and complicated procedures, thus leading to an unpredictable transformation of the chemical structures and limiting their applications. Herein, we develop a new insight to fabricating hemin-doped poly (3,4-ethylenedioxythiophene) (PEDOT) with controllable three-dimensional nanostructures via a one-step, tri-phase, self-assembled polymerization routine. We demonstrate that the hemin-induced synergistic effect results in a very high 4-electron oxygen reduction activity, a better stability, and free from methanol crossover effects even in a neutral phosphate buffer solution (PBS). |
| 语种 | 英语 |
| WOS记录号 | WOS:000336611000026 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51069]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Huan |
| 作者单位 | 1.Beihang Univ, Key Lab Bioinspired Smart Interfacial Sci & Techn, Minist Educ, Sch Chem & Environm, Beijing 100191, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA |
| 推荐引用方式 GB/T 7714 | Guo, Zhaoyan,Liu, Huan,Jiang, Congcong,et al. Biomolecule-Doped PEDOT with Three-Dimensional Nanostructures as Efficient Catalyst for Oxygen Reduction Reaction[J]. SMALL,2014,10(10):2087-2095. |
| APA | Guo, Zhaoyan.,Liu, Huan.,Jiang, Congcong.,Zhu, Ying.,Wan, Meixiang.,...&Jiang, Lei.(2014).Biomolecule-Doped PEDOT with Three-Dimensional Nanostructures as Efficient Catalyst for Oxygen Reduction Reaction.SMALL,10(10),2087-2095. |
| MLA | Guo, Zhaoyan,et al."Biomolecule-Doped PEDOT with Three-Dimensional Nanostructures as Efficient Catalyst for Oxygen Reduction Reaction".SMALL 10.10(2014):2087-2095. |
入库方式： OAI收割
来源：化学研究所
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