Self-Assembly of Channel Type beta-CD Dimers Induced by Dodecane
文献类型：期刊论文
| 作者 | Zhou, Chengcheng1,2; Cheng, Xinhao1; Zhao, Qiang1; Yan, Yun1; Wang, Jide2; Huang, Jianbin1 |
| 刊名 | SCIENTIFIC REPORTS
 |
| 出版日期 | 2014-12-22 |
| 卷号 | 4 |
| ISSN号 | 2045-2322 |
| DOI | 10.1038/srep07533 |
| 英文摘要 | Cyclodextrins (CDs) can hardly self-assemble into well-defined structures. Here we report if they preassemble into channel type dimers assisted by dodecane, well-defined vesicles and bricks can be formed. Unlike the traditional self-assembly of amphiphilic molecules driven by hydrophobic effect, the self-assembly of the channel type dodecane@2 beta-CD supramolecular building block is predoninantly driven by hydrogen-bonds. More water molecules are found in the lyophilized vesicles than in the bricks, suggesting water molecules play an important role in the self-assembly of the channel-type dimers of beta-CD. The amount of structural water in the self-assembly is closely related to the curvature of the final self-assembled structures. Our work reveals that the channel-type dimer of beta-CD may represent a new sort of building block for advanced structures. |
| 语种 | 英语 |
| WOS记录号 | WOS:000346722400001 |
| 出版者 | NATURE PUBLISHING GROUP |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51073]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yan, Yun |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China 2.Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Chengcheng,Cheng, Xinhao,Zhao, Qiang,et al. Self-Assembly of Channel Type beta-CD Dimers Induced by Dodecane[J]. SCIENTIFIC REPORTS,2014,4. |
| APA | Zhou, Chengcheng,Cheng, Xinhao,Zhao, Qiang,Yan, Yun,Wang, Jide,&Huang, Jianbin.(2014).Self-Assembly of Channel Type beta-CD Dimers Induced by Dodecane.SCIENTIFIC REPORTS,4. |
| MLA | Zhou, Chengcheng,et al."Self-Assembly of Channel Type beta-CD Dimers Induced by Dodecane".SCIENTIFIC REPORTS 4(2014). |
入库方式： OAI收割
来源：化学研究所
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