Synthesis of triphenylamine based polysiloxane as a blue phosphorescent host
文献类型：期刊论文
| 作者 | Sun, Dianming1; Yang, Zhaomin1; Sun, Xiaoli1; Li, Huihui1; Ren, Zhongjie1; Liu, Junteng2; Ma, Dongge3; Yan, Shouke1 |
| 刊名 | POLYMER CHEMISTRY
 |
| 出版日期 | 2014-09-07 |
| 卷号 | 5期号:17页码:5046-5052 |
| ISSN号 | 1759-9954 |
| DOI | 10.1039/c4py00450g |
| 英文摘要 | In this work, a triphenylamine based polysiloxane (PTPAMSi) has been successfully synthesized. The PTPAMSi exhibits a high decomposition temperature (T-d = 377 degrees C) and glass transition temperature (T-d = 63 degrees C). It also displays good film-forming ability, high morphological stability and good miscibility with the dopant Flrpic as revealed by atomic force microscopy (AFM). The silicon-oxygen linkage of PTPAMSi disrupts its conjugation and results in a sufficiently high triplet energy level (E-T = 2.9 eV). A Flrpic-based device using PTPAMSi as a host shows a turn-on voltage of 6.8 V, a maximum external quantum efficiency of 3.8%, and a maximum current efficiency of 7.6 cd A(-1). These results demonstrate that using polysiloxane to modify triphenylamine is a promising approach to improve the physical properties of triphenylamine while maintaining its photophysical and electrochemical properties. |
| 语种 | 英语 |
| WOS记录号 | WOS:000340581200022 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51077]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yan, Shouke |
| 作者单位 | 1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 2.Beijing Univ Chem Technol, Beijing Key Lab Membrane Sci & Technol, Beijing 100029, Peoples R China 3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Dianming,Yang, Zhaomin,Sun, Xiaoli,et al. Synthesis of triphenylamine based polysiloxane as a blue phosphorescent host[J]. POLYMER CHEMISTRY,2014,5(17):5046-5052. |
| APA | Sun, Dianming.,Yang, Zhaomin.,Sun, Xiaoli.,Li, Huihui.,Ren, Zhongjie.,...&Yan, Shouke.(2014).Synthesis of triphenylamine based polysiloxane as a blue phosphorescent host.POLYMER CHEMISTRY,5(17),5046-5052. |
| MLA | Sun, Dianming,et al."Synthesis of triphenylamine based polysiloxane as a blue phosphorescent host".POLYMER CHEMISTRY 5.17(2014):5046-5052. |
入库方式： OAI收割
来源：化学研究所
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