Inhibition of U(VI) Reduction by Synthetic and Natural Pyrite
文献类型：期刊论文
| 作者 | Yang, Zhuanwei1; Kang, Mingliang1,2; Ma, Bin1; Xie, Jinglin1; Chen, Fanrong2; Charlet, Laurent3; Liu, Chunli1 |
| 刊名 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2014-09-16 |
| 卷号 | 48期号:18页码:10716-10724 |
| ISSN号 | 0013-936X |
| DOI | 10.1021/es502181x |
| 英文摘要 | Reductive precipitation is an effective method of attenuating the mobility of uranium (U) in subsurface environments. The reduction of U(VI) by synthetic and naturally occurring pyrite was investigated at pH 3.0-9.5. In contrast to thermodynamic calculations that were used to predict UO2(s) precipitation, a mixed U(IV) and U(VI) product (e.g., U3O8/U4O9/U3O7) was only observed at pH 6.21-8.63 and 4.52-4.83 for synthetic and natural pyrite, respectively. Under acidic conditions, the reduction of UO22+ by surface-associated Fe2+ may not be favored because the mineral surface is nearly neutral or not negative enough. At high pH, the sorption of negatively charged U(VI) species is not favored on the negatively charged mineral surface. Thus, the redox reaction is not favored. Trace elements generally contained within the natural pyrite structure can affect the reactivity of pyrite and lead to a different result between the natural and synthetic pyrite. Because UO2(s) is extremely redox-sensitive toward U(VI), the observed UO2+x(s) phase reduction product indicates a surface reaction that is largely controlled by reaction kinetics and pyrite surface chemistry. These factors may explain why most laboratory experiments have observed incomplete U(VI) reduction on Fe(II)-bearing minerals. |
| 语种 | 英语 |
| WOS记录号 | WOS:000341801500024 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51215]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Kang, Mingliang |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Fundamental Sci Lab Radiochem & Radiat Chem, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Geochem, CAS Key Lab Mineral & Metallogeny, Guangzhou 510640, Guangdong, Peoples R China 3.Univ Grenoble 1, ISTerre, Environm Geochem Grp, F-38041 Grenoble, France |
| 推荐引用方式 GB/T 7714 | Yang, Zhuanwei,Kang, Mingliang,Ma, Bin,et al. Inhibition of U(VI) Reduction by Synthetic and Natural Pyrite[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2014,48(18):10716-10724. |
| APA | Yang, Zhuanwei.,Kang, Mingliang.,Ma, Bin.,Xie, Jinglin.,Chen, Fanrong.,...&Liu, Chunli.(2014).Inhibition of U(VI) Reduction by Synthetic and Natural Pyrite.ENVIRONMENTAL SCIENCE & TECHNOLOGY,48(18),10716-10724. |
| MLA | Yang, Zhuanwei,et al."Inhibition of U(VI) Reduction by Synthetic and Natural Pyrite".ENVIRONMENTAL SCIENCE & TECHNOLOGY 48.18(2014):10716-10724. |
入库方式： OAI收割
来源：化学研究所
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