中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A novel electrochemical chiral sensor for 3,4-dihydroxyphenylalanine based on the combination of single-walled carbon nanotubes, sulfuric acid and square wave voltammetry

文献类型:期刊论文

作者Chen, Lisha; Chang, Fengxia; Meng, Lingchen; Li, Meixian; Zhu, Zhiwei
刊名ANALYST
出版日期2014
卷号139期号:9页码:2243-2248
ISSN号0003-2654
DOI10.1039/c4an00098f
英文摘要We demonstrate, for the first time, an electrochemical sensor that provides antipodal signals upon application of square wave voltammetry (SWV), for enantioselective recognition of 3,4-dihydroxyphenylalanine based on chiral single-walled carbon nanotubes (SWCNTs) in the presence of sulphuric acid. Interestingly, the enantioselectivity was not observed using the common method of cyclic voltammetry (CV) but the SWV peak currents of enantiomers were found to be quite different and hence the enantiomers could be successfully recognized. Moreover, the antipodal signals provided by two SWV scan modes offer the possibility for results to be confirmed mutually, showing a great practical value and analytical application prospects.
语种英语
WOS记录号WOS:000334176400030
出版者ROYAL SOC CHEMISTRY
源URL[http://ir.iccas.ac.cn/handle/121111/51307]  
专题中国科学院化学研究所
通讯作者Zhu, Zhiwei
作者单位Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Chen, Lisha,Chang, Fengxia,Meng, Lingchen,et al. A novel electrochemical chiral sensor for 3,4-dihydroxyphenylalanine based on the combination of single-walled carbon nanotubes, sulfuric acid and square wave voltammetry[J]. ANALYST,2014,139(9):2243-2248.
APA Chen, Lisha,Chang, Fengxia,Meng, Lingchen,Li, Meixian,&Zhu, Zhiwei.(2014).A novel electrochemical chiral sensor for 3,4-dihydroxyphenylalanine based on the combination of single-walled carbon nanotubes, sulfuric acid and square wave voltammetry.ANALYST,139(9),2243-2248.
MLA Chen, Lisha,et al."A novel electrochemical chiral sensor for 3,4-dihydroxyphenylalanine based on the combination of single-walled carbon nanotubes, sulfuric acid and square wave voltammetry".ANALYST 139.9(2014):2243-2248.

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来源:化学研究所

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