Synthesis, characterization and properties of novel cellulose derivatives containing phosphorus: cellulose diphenyl phosphate and its mixed esters
文献类型：期刊论文
| 作者 | Xiao, Peng1,2; Zhang, Jinming1; Feng, Ye1,2; Wu, Jin1; He, Jiasong1; Zhang, Jun1 |
| 刊名 | CELLULOSE
 |
| 出版日期 | 2014-08-01 |
| 卷号 | 21期号:4页码:2369-2378 |
| 关键词 | Cellulose Ester Cellulose Diphenyl Phosphate Cellulose Mixed Ester Ionic Liquid |
| ISSN号 | 0969-0239 |
| DOI | 10.1007/s10570-014-0256-9 |
| 英文摘要 | Using ionic liquid 1-allyl-3-methylimidazolium chloride as reaction medium, a series of novel cellulose esters containing phosphorus including cellulose diphenyl phosphate (C-Dp) and cellulose acetate (CA)-diphenyl phosphate mixed esters was synthesized homogeneously. The degree of substitution was well controlled by altering reaction conditions, such as the molar ratio of the acylating reagents/ anhydroglucose unit and reaction time. The structure and thermal properties of cellulose esters were characterized by FTIR, NMR, wide-angle X-ray powder diffraction and differential scanning calorimetry. All the products possessed excellent solubility in some common organic solvents, and transparent films of cellulose esters were obtained by solution casting. In contrast to C-Dp, CA-diphenyl phosphate mixed esters showed clear glass transitions. More interestingly, these cellulose mixed esters exhibited thermoplastic behavior and could be processed by traditional melt processing methods. |
| 语种 | 英语 |
| WOS记录号 | WOS:000341490200015 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51339]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Jun |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Peng,Zhang, Jinming,Feng, Ye,et al. Synthesis, characterization and properties of novel cellulose derivatives containing phosphorus: cellulose diphenyl phosphate and its mixed esters[J]. CELLULOSE,2014,21(4):2369-2378. |
| APA | Xiao, Peng,Zhang, Jinming,Feng, Ye,Wu, Jin,He, Jiasong,&Zhang, Jun.(2014).Synthesis, characterization and properties of novel cellulose derivatives containing phosphorus: cellulose diphenyl phosphate and its mixed esters.CELLULOSE,21(4),2369-2378. |
| MLA | Xiao, Peng,et al."Synthesis, characterization and properties of novel cellulose derivatives containing phosphorus: cellulose diphenyl phosphate and its mixed esters".CELLULOSE 21.4(2014):2369-2378. |
入库方式： OAI收割
来源：化学研究所
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