Self-assembly and phase separation of amphiphilic dyads based on 4,7-bis(2-thienyl) benzothiodiazole and perylene diimide
文献类型：期刊论文
| 作者 | Peng, Jiang; Zhai, Feng; Guo, Xinyan; Jiang, Xinpeng; Ma, Yuguo |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2014 |
| 卷号 | 4期号:25页码:13078-13084 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c3ra47633b |
| 英文摘要 | To get highly ordered organic structures at the nanoscale, a series of new electronic donor-acceptor (D-A) dyads were synthesized. The dyads bearing different side chains (lipophilic or amphiphilic) or linkers (Long or Short) showed variable self-assembly behaviour. Long-linker dyads can fold in dilute solution, but the folding of short-linker dyads was not observed. Intermolecular D-A interactions and acceptor-acceptor (A-A) aggregation were proved to co-occur in chloroform for all four dyads. In the bulk state, amphiphilic dyads could overcome the intrinsic D-A interactions and achieve better D-A phase separation than lipophilic ones due to the incompatibility of the side chains. The dyad with a short-linker and amphiphilic side chains, S-amphi, had the ability to form a gel, and both of the amphiphilic dyads could form nanofibres. |
| 语种 | 英语 |
| WOS记录号 | WOS:000332485000055 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51377]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ma, Yuguo |
| 作者单位 | Peking Univ, BNLMS, Key Lab Polymer Chem & Phys, Minist Educ,Coll Chem, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, Jiang,Zhai, Feng,Guo, Xinyan,et al. Self-assembly and phase separation of amphiphilic dyads based on 4,7-bis(2-thienyl) benzothiodiazole and perylene diimide[J]. RSC ADVANCES,2014,4(25):13078-13084. |
| APA | Peng, Jiang,Zhai, Feng,Guo, Xinyan,Jiang, Xinpeng,&Ma, Yuguo.(2014).Self-assembly and phase separation of amphiphilic dyads based on 4,7-bis(2-thienyl) benzothiodiazole and perylene diimide.RSC ADVANCES,4(25),13078-13084. |
| MLA | Peng, Jiang,et al."Self-assembly and phase separation of amphiphilic dyads based on 4,7-bis(2-thienyl) benzothiodiazole and perylene diimide".RSC ADVANCES 4.25(2014):13078-13084. |
入库方式： OAI收割
来源：化学研究所
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