Switchable 2,2,2-Trifluoroethylation and gem-Difluorovinylation of Organoboronic Acids with 2,2,2-Trifluorodiazoethane
文献类型:期刊论文
作者 | Wu, Guojiao1,2; Deng, Yifan1,2; Wu, Chaoqiang1,2; Wang, Xi1,2; Zhang, Yan1,2; Wang, Jianbo1,2 |
刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
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出版日期 | 2014-07-01 |
期号 | 21页码:4477-4481 |
关键词 | Boron Fluorine Diazo Compounds Trifluoroethylation Gem-difluorovinylation |
ISSN号 | 1434-193X |
DOI | 10.1002/ejoc.201402597 |
英文摘要 | The transition-metal-free 2,2,2-trifluoroethylation and gem-difluorovinylation of arylboronic acids were developed. By employing different reaction conditions, these transformations provide both (2,2,2-trifluoroethyl)arenes and gem-difluorovinylarenes from arylboronic acids and 2,2,2-trifluorodiazoethane. The operation is simple and scalable with good functional group tolerance. |
语种 | 英语 |
WOS记录号 | WOS:000339493400007 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/51409] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wang, Jianbo |
作者单位 | 1.Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Wu, Guojiao,Deng, Yifan,Wu, Chaoqiang,et al. Switchable 2,2,2-Trifluoroethylation and gem-Difluorovinylation of Organoboronic Acids with 2,2,2-Trifluorodiazoethane[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2014(21):4477-4481. |
APA | Wu, Guojiao,Deng, Yifan,Wu, Chaoqiang,Wang, Xi,Zhang, Yan,&Wang, Jianbo.(2014).Switchable 2,2,2-Trifluoroethylation and gem-Difluorovinylation of Organoboronic Acids with 2,2,2-Trifluorodiazoethane.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(21),4477-4481. |
MLA | Wu, Guojiao,et al."Switchable 2,2,2-Trifluoroethylation and gem-Difluorovinylation of Organoboronic Acids with 2,2,2-Trifluorodiazoethane".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .21(2014):4477-4481. |
入库方式: OAI收割
来源:化学研究所
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