Arrested Coalescence of Droplets in PBD/PDMS Blends
文献类型：期刊论文
| 作者 | Zou Zhiming; Li Zhanwei; Fu Cuiliu; Sun Zhaoyan; An Lijia |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2014-02-10 |
| 卷号 | 35期号:2页码:421-426 |
| 关键词 | Immiscible Polymer Blend Arrested Coalescence Silica Nanoparticle Shear Flow Polybutadiene Polydimethylsiloxane |
| ISSN号 | 0251-0790 |
| DOI | 10.7503/cjcu20130674 |
| 英文摘要 | We investigated the effect of silica nanoparticle loading, dispersed phase fraction and shear rate on the arrested coalescence in immiscible blends of polybutadiene/polydimethylsiloxane (PBD/PDMS) under simple shear flow by an online optical-shear system. It was found that the size and regularity of the non-spherical PBD droplets resulted from arrested coalescence were determined by SiO2 nanoparticles loading, dispersed phase fraction and shear rate. At low SiO2 nanoparticle loading or high dispersed phase fractions, the coalescence of PBD droplets induced at low shear rate can be arrested by the nanoparticles at the interface, leading to the formation of large and irregular droplets. Increasing SiO2 nanoparticles loading, decreasing dispersed phase fraction or increasing shear rate can greatly decrease the size of the PBD droplets and improve their regularity. The results should be closely related to SiO2 nanoparticles coverage at the interface of the PBD droplets. |
| 语种 | 英语 |
| WOS记录号 | WOS:000332918400036 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51435]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fu Cuiliu |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zou Zhiming,Li Zhanwei,Fu Cuiliu,et al. Arrested Coalescence of Droplets in PBD/PDMS Blends[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2014,35(2):421-426. |
| APA | Zou Zhiming,Li Zhanwei,Fu Cuiliu,Sun Zhaoyan,&An Lijia.(2014).Arrested Coalescence of Droplets in PBD/PDMS Blends.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,35(2),421-426. |
| MLA | Zou Zhiming,et al."Arrested Coalescence of Droplets in PBD/PDMS Blends".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 35.2(2014):421-426. |
入库方式： OAI收割
来源：化学研究所
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