Synthesis and characterization of a new organically templated open-framework beryllium phosphite with 3, 4-connected networks
文献类型：期刊论文
| 作者 | Wang, Guo-Ming1; Zhang, Xiao1; Li, Jin-Hua1; Wang, Pei1; Wang, Zong-Hua1; Wang, Ying-Xia2; Lin, Jian-Hua2 |
| 刊名 | SOLID STATE SCIENCES
 |
| 出版日期 | 2014 |
| 卷号 | 27页码:55-59 |
| 关键词 | Beryllium Phosphite Hydrothermal Synthesis Crystal Structure Open-framework 12-ring Channel |
| ISSN号 | 1293-2558 |
| DOI | 10.1016/j.solidstatesciences.2013.11.008 |
| 英文摘要 | Employing diethylenetriamine (=dien) as a structure-directing agent, a new open-framework beryllium phosphite H(2)dien center dot Be-3(HPO3)(4) (1), has been synthesized hydrothermally and structurally characterized by single crystal X-ray diffraction. The structure of 1 features a (3, 4)-connected framework with 8- and 12-ring channels, which is constructed from strictly alternating BeO4 tetrahedra and HPO32- pseudo-pyramids. The 3-D framework possesses a pcu topology when the heptameric [Be-3(HPO3)(4)] clusters are regarded as 6-connected secondary building units. Crystal data: 1, monoclinic, C2/c (no. 15), a = 8.7350(3) angstrom, b = 15.1704(6) angstrom, c = 13.0851(4) angstrom, beta = 101.223(5)degrees, V = 1700.79(10) angstrom(3), Z = 4, R-1 = 0.0625, wR(2) = 0.1692. (C) 2013 Elsevier Masson SAS. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000331162300010 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51451]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Guo-Ming |
| 作者单位 | 1.Qingdao Univ, Teachers Coll, Coll Chem & Environm, Shandong 266071, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Guo-Ming,Zhang, Xiao,Li, Jin-Hua,et al. Synthesis and characterization of a new organically templated open-framework beryllium phosphite with 3, 4-connected networks[J]. SOLID STATE SCIENCES,2014,27:55-59. |
| APA | Wang, Guo-Ming.,Zhang, Xiao.,Li, Jin-Hua.,Wang, Pei.,Wang, Zong-Hua.,...&Lin, Jian-Hua.(2014).Synthesis and characterization of a new organically templated open-framework beryllium phosphite with 3, 4-connected networks.SOLID STATE SCIENCES,27,55-59. |
| MLA | Wang, Guo-Ming,et al."Synthesis and characterization of a new organically templated open-framework beryllium phosphite with 3, 4-connected networks".SOLID STATE SCIENCES 27(2014):55-59. |
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来源：化学研究所
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