A Tetrathiafulvalene-Based Electroactive Covalent Organic Framework
文献类型：期刊论文
| 作者 | Ding, Huimin1; Li, Yonghai2; Hu, Hui1; Sun, Yimeng2; Wang, Jianguo2; Wang, Caixing1; Wang, Cheng1; Zhang, Guanxin2; Wang, Baoshan1; Xu, Wei2 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2014-11-03 |
| 卷号 | 20期号:45页码:14614-14618 |
| 关键词 | Conducting Materials Covalent Organic Frameworks Electron Donor Microporous Materials Tetrathiafulvalene |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201405330 |
| 英文摘要 | Two-dimensional covalent organic frameworks (2D COFs) provide a unique platform for the molecular design of electronic and optoelectronic materials. Here, the synthesis and characterization of an electroactive COF containing the well-known tetrathiafulvalene (TTF) unit is reported. The TTF-COF crystallizes into 2D sheets with an eclipsed AA stacking motif, and shows high thermal stability and permanent porosity. The presence of TTF units endows the TTF-COF with electron-donating ability, which is characterized by cyclic voltammetry. In addition, the open frameworks of TTF-COF are amenable to doping with electron acceptors (e.g., iodine), and the conductivity of TTF-COF bulk samples can be improved by doping. Our results open up a reliable route for the preparation of well-ordered conjugated TTF polymers, which hold great potential for applications in fields from molecular electronics to energy storage. |
| 语种 | 英语 |
| WOS记录号 | WOS:000344358900012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51487]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Cheng |
| 作者单位 | 1.Wuhan Univ, Coll Chem & Mol Sci, Key Lab Biomed Polymers, Minist Educ, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Organ Solids Lab, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ding, Huimin,Li, Yonghai,Hu, Hui,et al. A Tetrathiafulvalene-Based Electroactive Covalent Organic Framework[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(45):14614-14618. |
| APA | Ding, Huimin.,Li, Yonghai.,Hu, Hui.,Sun, Yimeng.,Wang, Jianguo.,...&Zhang, Deqing.(2014).A Tetrathiafulvalene-Based Electroactive Covalent Organic Framework.CHEMISTRY-A EUROPEAN JOURNAL,20(45),14614-14618. |
| MLA | Ding, Huimin,et al."A Tetrathiafulvalene-Based Electroactive Covalent Organic Framework".CHEMISTRY-A EUROPEAN JOURNAL 20.45(2014):14614-14618. |
入库方式： OAI收割
来源：化学研究所
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