Synthesis, crystal structures and luminescence properties of europium and terbium picolinamide complexes
文献类型：期刊论文
| 作者 | Xue, Jun-Hui1,3; Hua, Xiao-Hui1; Yang, Li-Min2; Li, Wei-Hong1; Xu, Yi-Zhuang1; Zhao, Guo-Zhong4; Zhang, Gao-Hui4; Liu, Ke-Xin2; Chen, Jia-Er2; Wu, Jin-Guang1 |
| 刊名 | CHINESE CHEMICAL LETTERS
 |
| 出版日期 | 2014-06-01 |
| 卷号 | 25期号:6页码:887-891 |
| 关键词 | Picolinamide Ft-ir Complexation Crystal Structure Thz |
| ISSN号 | 1001-8417 |
| DOI | 10.1016/j.cclet.2014.01.012 |
| 英文摘要 | The novel coordination structures of europium and terbium chloride-picolinamide complexes (EuCl3 center dot(C6H6N2O)(2).center dot 5H(2)O, Eu-pa and TbCl3 center dot(C6H6N2O)(2)center dot 5H(2)O, Tb-pa) are reported. The crystal structures in the solid state are characterized by X-ray single crystal diffraction, FTIR, Raman, FIR, THz and luminescence spectroscopy. In the crystal structures, the pyridyl nitrogen and carbonyl oxygen atoms in picolinamide are coordinated to the metal ions to form a five-membered ring structure. The experimental results indicate the similar coordination structures of Eu and Tb-pa complexes and the changes of hydrogen bonds and conformation of the ligands induced by complexation. The results provide models for the coordination structures of lanthanide ions with ligands having amide groups. (C) 2014 Li-Min Yang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000340333800014 |
| 出版者 | ELSEVIER SCIENCE INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51491]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Li-Min |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Peking Univ, Sch Phys, Inst Heavy Ion Phys, State Key Lab Nucl Phys & Technol, Beijing 100871, Peoples R China 3.Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China 4.Capital Normal Univ, Dept Phys, Beijing 100037, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, Jun-Hui,Hua, Xiao-Hui,Yang, Li-Min,et al. Synthesis, crystal structures and luminescence properties of europium and terbium picolinamide complexes[J]. CHINESE CHEMICAL LETTERS,2014,25(6):887-891. |
| APA | Xue, Jun-Hui.,Hua, Xiao-Hui.,Yang, Li-Min.,Li, Wei-Hong.,Xu, Yi-Zhuang.,...&Wu, Jin-Guang.(2014).Synthesis, crystal structures and luminescence properties of europium and terbium picolinamide complexes.CHINESE CHEMICAL LETTERS,25(6),887-891. |
| MLA | Xue, Jun-Hui,et al."Synthesis, crystal structures and luminescence properties of europium and terbium picolinamide complexes".CHINESE CHEMICAL LETTERS 25.6(2014):887-891. |
入库方式： OAI收割
来源：化学研究所
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