中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Wall Slip Effect on Shear-Induced Crystallization Behavior of Isotactic Polypropylene Containing beta-Nucleating Agent

文献类型:期刊论文

作者Luo, Baojing1; Li, Hongfei2; Zhang, Yao1; Xue, Feifei1; Guan, Peipei1; Zhao, Jing1; Zhou, Chengbo1; Zhang, Wenyang1; Li, Jingqing1; Huo, Hong3
刊名INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
出版日期2014-08-27
卷号53期号:34页码:13513-13521
ISSN号0888-5885
DOI10.1021/ie502062k
英文摘要Shearing is unavoidable during the polymer process, and isotactic polypropylene (iPP) is one of the most used commercial polymers. iPP mixed with beta-nucleating agent TMB-5 was isothermally crystallized at 135 degrees C from melts under various shear conditions and investigated via synchrotron radiation small-angle and wide-angle X-ray scattering (SAXS and WAXS) techniques with CCD detector. The shear-induced crystalline structure and the orientation of the samples were studied according to the obtained WAXS and SAXS patterns. The results showed that both the crystallinity of alpha-iPP and beta-iPP are in direct proportion to the orientation degree rather than shear rate especially at high shear rate, which proves that wall slip should not be neglected when taking shear effect or rheological behavior into consideration.
语种英语
WOS记录号WOS:000340992000030
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/51537]  
专题中国科学院化学研究所
通讯作者Li, Hongfei
作者单位1.Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
3.Beijing Normal Univ, Inst Polymer Chem & Phys, Coll Chem, Beijing 100875, Peoples R China
4.Hubei Univ, Fac Mat Sci & Engn, Key Lab Green Preparat & Applicat Funct Mat, Minist Of Educ, Wuhan 430062, Peoples R China
5.Aalborg Univ, Dept Biotechnol Chem & Environm Engn, DK-9000 Aalborg, Denmark
推荐引用方式
GB/T 7714
Luo, Baojing,Li, Hongfei,Zhang, Yao,et al. Wall Slip Effect on Shear-Induced Crystallization Behavior of Isotactic Polypropylene Containing beta-Nucleating Agent[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2014,53(34):13513-13521.
APA Luo, Baojing.,Li, Hongfei.,Zhang, Yao.,Xue, Feifei.,Guan, Peipei.,...&Jiang, Shichun.(2014).Wall Slip Effect on Shear-Induced Crystallization Behavior of Isotactic Polypropylene Containing beta-Nucleating Agent.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,53(34),13513-13521.
MLA Luo, Baojing,et al."Wall Slip Effect on Shear-Induced Crystallization Behavior of Isotactic Polypropylene Containing beta-Nucleating Agent".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 53.34(2014):13513-13521.

入库方式: OAI收割

来源:化学研究所

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