Facile Fabrication of Polymeric Ionic Liquid Grafted Porous Polymer Monolith for Mixed-Mode High Performance Liquid Chromatography
文献类型:期刊论文
作者 | Li, Yaping1,2; Qi, Li1; Shen, Ying1,2; Zhang, Haizhi1,2; Ma, Huimin1 |
刊名 | CHINESE JOURNAL OF CHEMISTRY
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出版日期 | 2014-07-01 |
卷号 | 32期号:7页码:619-625 |
关键词 | Porous Polymer Monolith Ionic Liquid Mixed-mode Chromatography |
ISSN号 | 1001-604X |
DOI | 10.1002/cjoc.201400188 |
英文摘要 | A novel polymeric ionic liquid grafted porous polymer monolith has been facilely fabricated for mixed-mode chromatography. The column is prepared from poly (glycidyl methacrylate-co-ethylene dimethacrylate) monolith through hydrolyzation of the epoxy moieties into hydroxyl groups, followed by "grafting from" polymerization of ionic liquid of 1-vinyl-3-butylimidazolium chloride. Successful modification is characterized by scanning electron microscope, infrared spectroscopy, elemental analysis and mercury intrusion porosimetry. The HPLC performance of developed column is evaluated by separating acidic vitamin B analytes, neutral steroids and basic aromatic amines in mixed-mode chromatography on a single column, respectively. The ionic liquid affords the monolith with both enhanced separation ability and improved column efficiency. |
语种 | 英语 |
WOS记录号 | WOS:000339520300009 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/51561] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Qi, Li |
作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Analyt Chem Living Biosyst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Yaping,Qi, Li,Shen, Ying,et al. Facile Fabrication of Polymeric Ionic Liquid Grafted Porous Polymer Monolith for Mixed-Mode High Performance Liquid Chromatography[J]. CHINESE JOURNAL OF CHEMISTRY,2014,32(7):619-625. |
APA | Li, Yaping,Qi, Li,Shen, Ying,Zhang, Haizhi,&Ma, Huimin.(2014).Facile Fabrication of Polymeric Ionic Liquid Grafted Porous Polymer Monolith for Mixed-Mode High Performance Liquid Chromatography.CHINESE JOURNAL OF CHEMISTRY,32(7),619-625. |
MLA | Li, Yaping,et al."Facile Fabrication of Polymeric Ionic Liquid Grafted Porous Polymer Monolith for Mixed-Mode High Performance Liquid Chromatography".CHINESE JOURNAL OF CHEMISTRY 32.7(2014):619-625. |
入库方式: OAI收割
来源:化学研究所
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