Application of "Click" Chemistry to the Construction of Supramolecular Functional Systems
文献类型：期刊论文
| 作者 | Xu, Liang1,2; Li, Yongjun1; Li, Yuliang1 |
| 刊名 | ASIAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2014-05-01 |
| 卷号 | 3期号:5页码:582-602 |
| 关键词 | Bioactive Macrocycles Click Chemistry Molecular Machines Receptors Triazoles |
| ISSN号 | 2193-5807 |
| DOI | 10.1002/ajoc.201300245 |
| 英文摘要 | The aim of this article is to summarize the recent advances in the synthesis of functional systems based on Cu-I-catalyzed azide-alkyne cycloaddition reaction. This reaction has the ability to exclusively afford 1,4-disubstituted 1,2,3-triazoles regioselectively, which have several features. First, such triazoles have a polarized CH bond, which could be used as a H-bond donor. Second, its atom arrangement and electronic properties are similar to those of a peptide bond, making it a candidate for an amide surrogate. Third, it has three nitrogen atoms, two of which could be used as coordinating sites for metal ions. Based on these features, 1,2,3-triazoles have potential applications in the construction of supramolecular functional systems. The design and synthesis strategies for anion receptors, bioactive macrocycles, and molecular machines are reviewed here. And in this scope we focus on foldamer-based receptors, macrocycle-based receptors, macrocyclic carbohydrates, macrocyclic peptides, catenanes, and rotaxanes. |
| 语种 | 英语 |
| WOS记录号 | WOS:000335518800001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51563]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Yongjun |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solid, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Liang,Li, Yongjun,Li, Yuliang. Application of "Click" Chemistry to the Construction of Supramolecular Functional Systems[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2014,3(5):582-602. |
| APA | Xu, Liang,Li, Yongjun,&Li, Yuliang.(2014).Application of "Click" Chemistry to the Construction of Supramolecular Functional Systems.ASIAN JOURNAL OF ORGANIC CHEMISTRY,3(5),582-602. |
| MLA | Xu, Liang,et al."Application of "Click" Chemistry to the Construction of Supramolecular Functional Systems".ASIAN JOURNAL OF ORGANIC CHEMISTRY 3.5(2014):582-602. |
入库方式： OAI收割
来源：化学研究所
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