One-Pot Ultrafast Self-Assembly of Autofluorescent Polyphenol-Based Core@Shell Nanostructures and Their Selective Antibacterial Applications
文献类型：期刊论文
| 作者 | Fei, Jinbo1; Zhao, Jie1; Du, Cuiling2; Wang, Anhe2; Zhang, He1; Dai, Luru2; Li, Junbai1,2 |
| 刊名 | ACS NANO
 |
| 出版日期 | 2014-08-01 |
| 卷号 | 8期号:8页码:8529-8536 |
| 关键词 | Core-shell Nanostructure Polyphenol Autofluorescence Selective Antibacterial Materials Microwave Chemistry |
| ISSN号 | 1936-0851 |
| DOI | 10.1021/nn504077c |
| 英文摘要 | We demonstrate that large-scale autofluorescent tea polyphenol (TP)-based core@shell nanostructures can be assembled by one-pot preparation under microwave irradiation within 1 min. The formation mechanism of the heterogeneous well-defined core@shell nanocomposites involves microwave-assisted oxidation inducing self assembly and directed aggregation. The strategy is general to construct Ag@TP and Au@TP nanocomposites. Moreover, a simple galvanic replacement reaction was introduced to synthesize hollow Au/Ag@TP bioconjugates with near-infrared (NIR) absorption, which could be exploited for NIR cancer diagnosis and treatment. It could be expected that more complex alloy@TP nanostructures can be obtained under proper reaction conditions. Furthermore, as a first application, it is shown that the heterogeneous Ag@TP nanostructures can strongly inhibit Escherichia cob growth, while they exhibit no obvious normal cell toxicity. The sharp contrast of the two effects promises that the nanocomposites are excellent low toxicity biomaterials for selective antibacterial treatment. |
| 语种 | 英语 |
| WOS记录号 | WOS:000340992300103 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51657]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Junbai |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fei, Jinbo,Zhao, Jie,Du, Cuiling,et al. One-Pot Ultrafast Self-Assembly of Autofluorescent Polyphenol-Based Core@Shell Nanostructures and Their Selective Antibacterial Applications[J]. ACS NANO,2014,8(8):8529-8536. |
| APA | Fei, Jinbo.,Zhao, Jie.,Du, Cuiling.,Wang, Anhe.,Zhang, He.,...&Li, Junbai.(2014).One-Pot Ultrafast Self-Assembly of Autofluorescent Polyphenol-Based Core@Shell Nanostructures and Their Selective Antibacterial Applications.ACS NANO,8(8),8529-8536. |
| MLA | Fei, Jinbo,et al."One-Pot Ultrafast Self-Assembly of Autofluorescent Polyphenol-Based Core@Shell Nanostructures and Their Selective Antibacterial Applications".ACS NANO 8.8(2014):8529-8536. |
入库方式： OAI收割
来源：化学研究所
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