Synthesis, Characterization, and Electron-Transport Properties of a pi-Conjugated Heteromacrocycle: A Selenium-Bridged Neutral Annulene
文献类型：期刊论文
| 作者 | Liu, Hang1,2; Qin, Yunke1,2; Xu, Wei1; Zhu, Daoben1 |
| 刊名 | ASIAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2014-12-01 |
| 卷号 | 3期号:12页码:1302-1307 |
| 关键词 | Annulenes Macrocycles Organic Field-effect Transistors Selenium Semiconductors |
| ISSN号 | 2193-5807 |
| DOI | 10.1002/ajoc.201402157 |
| 英文摘要 | An aromatic heteromacrocycle, selenium bridged neutral annulene 5,16-diphenyltetraselenolo-[22] annulene[2,1,2,1] (DPTSA) was synthesized through a convenient four-step procedure. DPTSA is a symmetrical macrocyclic architecture consisting of four selenophene units linked with unsaturated carboncarbon bonds. DPTSA was shown to have high aromaticity by H-1 NMR and UV/vis absorption spectra. Its electrochemical properties and thermostability were studied. A thin-film transistor based on DPTSA was fabricated to evaluate the possibility of its application in organic field-effect transistors (OFETs). DPTSA performed as a p-type semiconductor with the best hole mobility of 2.8 x 10(-3) cm(2)V(-1)S(-1) and the on/off ratio of 1.0 x 10(5). The thin-film morphology of devices based on DPTSA was also characterized to preliminarily reveal the structure-property relationships. |
| 语种 | 英语 |
| WOS记录号 | WOS:000346073200009 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51701]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xu, Wei |
| 作者单位 | 1.Chinese Acad Sci, Organ Solids Lab, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Hang,Qin, Yunke,Xu, Wei,et al. Synthesis, Characterization, and Electron-Transport Properties of a pi-Conjugated Heteromacrocycle: A Selenium-Bridged Neutral Annulene[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2014,3(12):1302-1307. |
| APA | Liu, Hang,Qin, Yunke,Xu, Wei,&Zhu, Daoben.(2014).Synthesis, Characterization, and Electron-Transport Properties of a pi-Conjugated Heteromacrocycle: A Selenium-Bridged Neutral Annulene.ASIAN JOURNAL OF ORGANIC CHEMISTRY,3(12),1302-1307. |
| MLA | Liu, Hang,et al."Synthesis, Characterization, and Electron-Transport Properties of a pi-Conjugated Heteromacrocycle: A Selenium-Bridged Neutral Annulene".ASIAN JOURNAL OF ORGANIC CHEMISTRY 3.12(2014):1302-1307. |
入库方式： OAI收割
来源：化学研究所
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