Self-Assembly of Ultralong Polyion Nanoladders Facilitated by Ionic Recognition and Molecular Stiffness
文献类型：期刊论文
| 作者 | Xu, Limin1; Jiang, Lingiang1; Drechsler, Markus2; Sun, Yu1; Liu, Zhirong1; Huang, Jianbin1; Tang, Ben Zhong3; Li, Zhibo4; Stuart, Martien A. Cohen5; Yan, Yun1 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2014-02-05 |
| 卷号 | 136期号:5页码:1942-1947 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/ja410443n |
| 英文摘要 | It is hard to obtain spatially ordered nanostructures via the polyion complexation process due to the inherent flexibility of polymers and isotropicity of ionic interactions. Here we report the formation of polyion assemblies with well-defined, periodically regular internal structure by imparting the proper stiffness to the molecular tile. A stiff bisligand TPE-C4-L2 was designed which is able to form a negatively charged supramolecular polyelectrolyte with transition metal ions. This supramolecular polyelectrolyte slowly self-assembled into polydispersed flat sheets with cocoon-like patterns. Upon the addition of an oppositely charged Ordinary polyelectrolyte, the polydispersed cocoons immediately transformed into ultralong, uniform nanoladders as a result of matched ionic density recognition. The supramolecular polyelectrolytes assembled side-by-side, and the negative charges aligned in an array. This structure forced the positively charged polymers to lie along the negative charges so that the perpendicular arrangement of the oppositely charged chains was achieved. Such precise charge recognition will provide insight into the design of advanced materials with hierarchical self-assembled structures. |
| 语种 | 英语 |
| WOS记录号 | WOS:000331493700044 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51747]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, Jianbin |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Beijing 100871, Peoples R China 2.Univ Bayreuth, Bayreuth Inst Macromol Res BIMF TEM, D-95440 Bayreuth, Germany 3.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China 4.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 5.Wageningen Univ, Lab Phys Chem & Colloid Sci, NL-6703 HB Wageningen, Netherlands |
| 推荐引用方式 GB/T 7714 | Xu, Limin,Jiang, Lingiang,Drechsler, Markus,et al. Self-Assembly of Ultralong Polyion Nanoladders Facilitated by Ionic Recognition and Molecular Stiffness[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2014,136(5):1942-1947. |
| APA | Xu, Limin.,Jiang, Lingiang.,Drechsler, Markus.,Sun, Yu.,Liu, Zhirong.,...&Yan, Yun.(2014).Self-Assembly of Ultralong Polyion Nanoladders Facilitated by Ionic Recognition and Molecular Stiffness.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,136(5),1942-1947. |
| MLA | Xu, Limin,et al."Self-Assembly of Ultralong Polyion Nanoladders Facilitated by Ionic Recognition and Molecular Stiffness".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 136.5(2014):1942-1947. |
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来源：化学研究所
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