中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Single-fluorophore-based fluorescent probes enable dual-channel detection of Ag+ and Hg2+ with high selectivity and sensitivity

文献类型:期刊论文

作者Lv, Yanlin1; Zhu, Lili2; Liu, Heng1; Wu, Yishi3,4; Chen, Zili2; Fu, Hongbing3,4; Tian, Zhiyuan1
刊名ANALYTICA CHIMICA ACTA
出版日期2014-08-11
卷号839页码:74-82
关键词Fluorescent Probe Silver Ions Mercury Ions Dual-channel Detection
ISSN号0003-2670
DOI10.1016/j.aca.2014.06.010
英文摘要A new type of fluorescent probe capable of detecting Ag+ and Hg2+ in two independent channels was developed in the present work. Specifically, in CH3CN-MOPS mixed solvents with CH3CN/MOPS ratio (v/v) of 15/85, this type of probe fluoresced weakly, and the addition of Ag+ remarkably induced fluorescence enhancement of the probe. In CH3CN-MOPS mixed solvents with the percentage of CH3CN increased up to 65%, the probe was highly fluorescent and addition of Hg2+ dramatically induced the fluorescence quenching. Thus, using such single-fluorophore-based probe and tuning the polarity of the mixed solvent, Ag+(,) and Hg2(+) can be detected in independent channels with high selectivity and sensitivity. As a result, the mutual interference usually encountered in most cases of Ag+ and Hg2(+) sensing owing to the similar fluorescence response that these two ions induced, can be effectively circumvented by using the probes developed herein. (C) 2014 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000339992000010
出版者ELSEVIER SCIENCE BV
源URL[http://ir.iccas.ac.cn/handle/121111/51771]  
专题中国科学院化学研究所
通讯作者Wu, Yishi
作者单位1.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China
2.Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Lv, Yanlin,Zhu, Lili,Liu, Heng,et al. Single-fluorophore-based fluorescent probes enable dual-channel detection of Ag+ and Hg2+ with high selectivity and sensitivity[J]. ANALYTICA CHIMICA ACTA,2014,839:74-82.
APA Lv, Yanlin.,Zhu, Lili.,Liu, Heng.,Wu, Yishi.,Chen, Zili.,...&Tian, Zhiyuan.(2014).Single-fluorophore-based fluorescent probes enable dual-channel detection of Ag+ and Hg2+ with high selectivity and sensitivity.ANALYTICA CHIMICA ACTA,839,74-82.
MLA Lv, Yanlin,et al."Single-fluorophore-based fluorescent probes enable dual-channel detection of Ag+ and Hg2+ with high selectivity and sensitivity".ANALYTICA CHIMICA ACTA 839(2014):74-82.

入库方式: OAI收割

来源:化学研究所

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