A Protic Ionic Liquid Catalyzes CO2 Conversion at Atmospheric Pressure and Room Temperature: Synthesis of Quinazoline-2,4-(1H,3H)-diones
文献类型：期刊论文
| 作者 | Zhao, Yanfei; Yu, Bo; Yang, Zhenzhen; Zhang, Hongye; Hao, Leiduan; Gao, Xiang; Liu, Zhimin |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2014-06-01 |
| 卷号 | 53期号:23页码:5922-5925 |
| 关键词 | Carbon Dioxide Fixation Heterocylces Ionic Liquids Reaction Mechanism Synthetic Methods |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201400521 |
| 英文摘要 | The chemical fixation of CO2 under mild reaction conditions is of significance from a sustainable chemistry viewpoint. Herein a CO2-reactive protic ionic liquid (PIL), [HDBU+][TFE-], was designed by neutralization of the superbase 1,8-diazabicyclo[5.4.0] undec-7-ene (DBU) with a weak proton donor trifluoroethanol (TFE). As a bifunctional catalyst for simultaneously activating CO2 and the substrate, this PIL displayed excellent performance in catalyzing the reactions of CO2 with 2-aminobenzonitriles at atmospheric pressure and room temperature, thus producing a series of quinazoline-2,4(1H,3H)-diones in excellent yields. |
| 语种 | 英语 |
| WOS记录号 | WOS:000337094200033 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51773]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Zhimin |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Yanfei,Yu, Bo,Yang, Zhenzhen,et al. A Protic Ionic Liquid Catalyzes CO2 Conversion at Atmospheric Pressure and Room Temperature: Synthesis of Quinazoline-2,4-(1H,3H)-diones[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(23):5922-5925. |
| APA | Zhao, Yanfei.,Yu, Bo.,Yang, Zhenzhen.,Zhang, Hongye.,Hao, Leiduan.,...&Liu, Zhimin.(2014).A Protic Ionic Liquid Catalyzes CO2 Conversion at Atmospheric Pressure and Room Temperature: Synthesis of Quinazoline-2,4-(1H,3H)-diones.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(23),5922-5925. |
| MLA | Zhao, Yanfei,et al."A Protic Ionic Liquid Catalyzes CO2 Conversion at Atmospheric Pressure and Room Temperature: Synthesis of Quinazoline-2,4-(1H,3H)-diones".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.23(2014):5922-5925. |
入库方式： OAI收割
来源：化学研究所
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