Acceptor-Donor-Acceptor Small Molecules Based on Indacenodithiophene for Efficient Organic Solar Cells
文献类型：期刊论文
| 作者 | Bai, Huitao1,3; Wang, Yifan1,3; Cheng, Pei1,3; Li, Yongfang1; Zhu, Daoben1; Zhan, Xiaowei2 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2014-06-11 |
| 卷号 | 6期号:11页码:8426-8433 |
| 关键词 | Small Molecule Solar Cells Indacenodithiophene Alkyl Cyanoacetate Rhodanine |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/am501316y |
| 英文摘要 | Four A-D-A type small molecules using 4,4,9,9-tetrakis(4-hexylphenyl)- indaceno[1,2-b:5,6-b']dithiophene as central building block, bithiophene or terthiophene as pi-bridges, alkyl cyanoacetate or rhodanine as end acceptor groups were synthesized and investigated as electron donors in solution-processed organic solar cells (OSCs). These molecules showed excellent thermal stability with decomposition temperatures over 360 degrees C, relatively low HOMO levels of -5.18 to -5.22 eV, and strong optical absorption from 350 to 670 nm with high molar extinction coefficient of 1.1 x 10(5) to 1.6 x 10(5) M-1 cm(-1) in chloroform solution. OSCs based on blends of these molecules and PC71BM achieved average power conversion efficiencies of 2.32 to 5.09% (the best 5.32%) after thermal annealing. The effects of thiophene bridge length and end acceptor groups on absorption, energy level, charge transport, morphology, and photovoltaic properties of the molecules were investigated. |
| 语种 | 英语 |
| WOS记录号 | WOS:000337336900057 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51801]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhan, Xiaowei |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Peking Univ, Coll Engn, Dept Mat Sci & Engn, Beijing 100871, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bai, Huitao,Wang, Yifan,Cheng, Pei,et al. Acceptor-Donor-Acceptor Small Molecules Based on Indacenodithiophene for Efficient Organic Solar Cells[J]. ACS APPLIED MATERIALS & INTERFACES,2014,6(11):8426-8433. |
| APA | Bai, Huitao,Wang, Yifan,Cheng, Pei,Li, Yongfang,Zhu, Daoben,&Zhan, Xiaowei.(2014).Acceptor-Donor-Acceptor Small Molecules Based on Indacenodithiophene for Efficient Organic Solar Cells.ACS APPLIED MATERIALS & INTERFACES,6(11),8426-8433. |
| MLA | Bai, Huitao,et al."Acceptor-Donor-Acceptor Small Molecules Based on Indacenodithiophene for Efficient Organic Solar Cells".ACS APPLIED MATERIALS & INTERFACES 6.11(2014):8426-8433. |
入库方式： OAI收割
来源：化学研究所
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