Intermolecular Interactions and 3D Structure in Cellulose-NaOH-Urea Aqueous System
文献类型：期刊论文
| 作者 | Jiang, Zhiwei1,2; Fang, Yan2; Xiang, Junfeng1; Ma, Yanping1; Lu, Ang2; Kang, Hongliang1; Huang, Yong1; Guo, Hongxia1; Liu, Ruigang1; Zhang, Lina2 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2014-08-28 |
| 卷号 | 118期号:34页码:10250-10257 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp501408e |
| 英文摘要 | The dissolution of cellulose in NaOH/urea aqueous solution at low temperature is a key finding in cellulose science and technology. In this paper, N-15 and Na-23 NMR experiments were carried out to clarify the intermolecular interactions in cellulose/NaOH/urea aqueous solution. It was found that there are direct interactions between OH- anions and amino groups of urea through hydrogen bonds and no direct interaction between urea and cellulose. Moreover, Na+ ions can interact with both cellulose and urea in an aqueous system. These interactions lead to the formation of cellulose-NaOH-urea-H2O inclusion complexes (ICs). Na-23 relaxation results confirmed that the formation of urea-OH- clusters can effectively enhance the stability of Na+ ions that attracted to cellulose chains. Low temperature can enhance the hydrogen bonding interaction between OH- ions and urea and improve the binding ability of the NaOH/urea/H2O clusters that attached to cellulose chains. Cryo-TEM observation confirmed the formation of cellulose-NaOH-urea-H2O ICs, which is in extended conformation with mean diameter of about 3.6 nm and mean length of about 300 nm. Possible 3D structure of the ICs was proposed by the M06-2X/6-31+G(d) theoretical calculation, revealing the O3H center dot center dot center dot O5 intramolecular hydrogen bonds could remain in the ICs. This work clarified the interactions in cellulose/NaOH/urea aqueous solution and the 3D structure of the cellulose chain in dilute cellulose/NaOH/urea aqueous solution. |
| 语种 | 英语 |
| WOS记录号 | WOS:000341121800025 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51843]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Ruigang |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 2.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Zhiwei,Fang, Yan,Xiang, Junfeng,et al. Intermolecular Interactions and 3D Structure in Cellulose-NaOH-Urea Aqueous System[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2014,118(34):10250-10257. |
| APA | Jiang, Zhiwei.,Fang, Yan.,Xiang, Junfeng.,Ma, Yanping.,Lu, Ang.,...&Zhang, Lina.(2014).Intermolecular Interactions and 3D Structure in Cellulose-NaOH-Urea Aqueous System.JOURNAL OF PHYSICAL CHEMISTRY B,118(34),10250-10257. |
| MLA | Jiang, Zhiwei,et al."Intermolecular Interactions and 3D Structure in Cellulose-NaOH-Urea Aqueous System".JOURNAL OF PHYSICAL CHEMISTRY B 118.34(2014):10250-10257. |
入库方式： OAI收割
来源：化学研究所
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