Palladium-Catalyzed C( sp(3))- H Activation: A Facile Method for the Synthesis of 3,4-Dihydroquinolinone Derivatives**
文献类型：期刊论文
| 作者 | Yan, Jia-Xuan1,2; Li, Hu1,2; Liu, Xiang-Wei1,2; Shi, Jiang-Ling1,2; Wang, Xin1,2; Shi, Zhang-Jie1,2,3 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2014-05-05 |
| 卷号 | 53期号:19页码:4945-4949 |
| 关键词 | Ch Activation Dihydroquinolinones Palladacycles Palladium Synthetic Methods |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201402562 |
| 英文摘要 | 3,4-Dihydroquinolinones were synthesized by the palladium-catalyzed, oxidative-addition-initiated activation and arylation of inert C(sp(3))H bonds. Pd(OAc)(2) and P(o-tol)(3) were used as the catalyst and ligand, respectively, to improve the efficiency of the reaction. A further advantage of this reaction is that it could be performed in air. A relatively rare seven-membered palladacycle was proposed as a key intermediate of the catalytic cycle. |
| 语种 | 英语 |
| WOS记录号 | WOS:000335202700034 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/51853]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shi, Zhang-Jie |
| 作者单位 | 1.Peking Univ, PKU Green Chem Ctr, Beijing Natl Lab Mol Sci BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China 3.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan, Jia-Xuan,Li, Hu,Liu, Xiang-Wei,et al. Palladium-Catalyzed C( sp(3))- H Activation: A Facile Method for the Synthesis of 3,4-Dihydroquinolinone Derivatives**[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(19):4945-4949. |
| APA | Yan, Jia-Xuan,Li, Hu,Liu, Xiang-Wei,Shi, Jiang-Ling,Wang, Xin,&Shi, Zhang-Jie.(2014).Palladium-Catalyzed C( sp(3))- H Activation: A Facile Method for the Synthesis of 3,4-Dihydroquinolinone Derivatives**.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(19),4945-4949. |
| MLA | Yan, Jia-Xuan,et al."Palladium-Catalyzed C( sp(3))- H Activation: A Facile Method for the Synthesis of 3,4-Dihydroquinolinone Derivatives**".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.19(2014):4945-4949. |
入库方式： OAI收割
来源：化学研究所
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