Cu(I)-Catalyzed Cross-Coupling of Conjugated Ene-yne-ketones and Terminal Alkynes: Synthesis of Furan-Substituted Allenes
文献类型:期刊论文
作者 | Hu, Fangdong1,2,3; Xia, Ying2,3; Ma, Chen1; Zhang, Yan2,3; Wang, Jianbo2,3 |
刊名 | ORGANIC LETTERS
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出版日期 | 2014-08-15 |
卷号 | 16期号:16页码:4082-4085 |
ISSN号 | 1523-7060 |
DOI | 10.1021/ol501747f |
英文摘要 | A new method for the synthesis of furan-substituted allenes via Cu(I)-catalyzed coupling of conjugated ene-yne-ketones with terminal alkynes has been developed. A wide range of functional groups are tolerated, and the products are obtained in good to excellent yields under mild conditions. A copper carbene migratory insertion is proposed as the key step in this transformation with conjugated ene-yne-ketones as carbene precursors. |
语种 | 英语 |
WOS记录号 | WOS:000340517200007 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/51971] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Ma, Chen |
作者单位 | 1.Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China 2.Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China 3.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Hu, Fangdong,Xia, Ying,Ma, Chen,et al. Cu(I)-Catalyzed Cross-Coupling of Conjugated Ene-yne-ketones and Terminal Alkynes: Synthesis of Furan-Substituted Allenes[J]. ORGANIC LETTERS,2014,16(16):4082-4085. |
APA | Hu, Fangdong,Xia, Ying,Ma, Chen,Zhang, Yan,&Wang, Jianbo.(2014).Cu(I)-Catalyzed Cross-Coupling of Conjugated Ene-yne-ketones and Terminal Alkynes: Synthesis of Furan-Substituted Allenes.ORGANIC LETTERS,16(16),4082-4085. |
MLA | Hu, Fangdong,et al."Cu(I)-Catalyzed Cross-Coupling of Conjugated Ene-yne-ketones and Terminal Alkynes: Synthesis of Furan-Substituted Allenes".ORGANIC LETTERS 16.16(2014):4082-4085. |
入库方式: OAI收割
来源:化学研究所
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