Synthesis and Reactions of Triptycene-Derived Bromocalix[5] arenes: Conformational Transformation from Cone to 1,2-Alternate
文献类型：期刊论文
| 作者 | Xia, Yu-Xiang1,2; Han, Ying1; Chen, Chuan-Feng1 |
| 刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2014-03-01 |
| 卷号 | 2014期号:9页码:1976-1983 |
| 关键词 | Calixarenes Conformation Analysis Cross-coupling Macrocycles Fused-ring Systems |
| ISSN号 | 1434-193X |
| DOI | 10.1002/ejoc.201301668 |
| 英文摘要 | Triptycene-derived p-dibromocalix[5]arene was synthesized by a fragment-coupling approach, whereas treatment of the triptycene-derived calix[5]arene containing three p-tert-butyl phenol groups and a 1,8-dimethoxytriptycene moiety with excess bromine in dichloromethane at room temperature produced triptycene-derived p-pentabromocalix[5]arene directly. Methyl etherification and Suzuki coupling reactions were then carried out. As a result, a series of triptycene-derived calix[5]arene derivatives in fixed cone and 1,2-alternate conformations were obtained. Moreover, conformation transformations of triptycene-derived calix[5]arenes from cone to 1,2-alternate forms could also be achieved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000332761300023 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52035]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, Chuan-Feng |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Yu-Xiang,Han, Ying,Chen, Chuan-Feng. Synthesis and Reactions of Triptycene-Derived Bromocalix[5] arenes: Conformational Transformation from Cone to 1,2-Alternate[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2014,2014(9):1976-1983. |
| APA | Xia, Yu-Xiang,Han, Ying,&Chen, Chuan-Feng.(2014).Synthesis and Reactions of Triptycene-Derived Bromocalix[5] arenes: Conformational Transformation from Cone to 1,2-Alternate.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2014(9),1976-1983. |
| MLA | Xia, Yu-Xiang,et al."Synthesis and Reactions of Triptycene-Derived Bromocalix[5] arenes: Conformational Transformation from Cone to 1,2-Alternate".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY 2014.9(2014):1976-1983. |
入库方式： OAI收割
来源：化学研究所
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