Communication: Determining the structure of the N2Ar van der Waals complex with laser-based channel-selected Coulomb explosion
文献类型：期刊论文
| 作者 | Wu, Chengyin1,2; Wu, Cong1; Song, Di3; Su, Hongmei3; Xie, Xiguo1; Li, Min1; Deng, Yongkai1; Liu, Yunquan1,2; Gong, Qihuang1,2 |
| 刊名 | JOURNAL OF CHEMICAL PHYSICS
 |
| 出版日期 | 2014-04-14 |
| 卷号 | 140期号:14 |
| ISSN号 | 0021-9606 |
| DOI | 10.1063/1.4871205 |
| 英文摘要 | We experimentally reconstructed the structure of the N2Ar van der Waals complex with the technique of laser-based channel-selected Coulomb explosion imaging. The internuclear distance between the N-2 center of mass and the Ar atom, i.e., the length of the van der Waals bond, was determined to be 3.88 angstrom from the two-body explosion channels. The angle between the van der Waals bond and the N-2 principal axis was determined to be 90. from the three-body explosion channels. The reconstructed structure was contrasted with our high level ab initio calculations. The agreement demonstrated the potential application of laser-based Coulomb explosion in imaging transient molecular structure, particularly for floppy van der Waals complexes, whose structures remain difficult to be determined by conventional spectroscopic methods. (C) 2014 AIP Publishing LLC. |
| 语种 | 英语 |
| WOS记录号 | WOS:000334836600001 |
| 出版者 | AMER INST PHYSICS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52059]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wu, Chengyin |
| 作者单位 | 1.Peking Univ, Dept Phys, State Key Lab Mesoscop Phys, Beijing 100871, Peoples R China 2.Collaborat Innovat Ctr Quantum Matter, Beijing, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Chengyin,Wu, Cong,Song, Di,et al. Communication: Determining the structure of the N2Ar van der Waals complex with laser-based channel-selected Coulomb explosion[J]. JOURNAL OF CHEMICAL PHYSICS,2014,140(14). |
| APA | Wu, Chengyin.,Wu, Cong.,Song, Di.,Su, Hongmei.,Xie, Xiguo.,...&Gong, Qihuang.(2014).Communication: Determining the structure of the N2Ar van der Waals complex with laser-based channel-selected Coulomb explosion.JOURNAL OF CHEMICAL PHYSICS,140(14). |
| MLA | Wu, Chengyin,et al."Communication: Determining the structure of the N2Ar van der Waals complex with laser-based channel-selected Coulomb explosion".JOURNAL OF CHEMICAL PHYSICS 140.14(2014). |
入库方式： OAI收割
来源：化学研究所
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