Versatile inorganic-organic hybrid WOx-ethylenediamine nanowires: Synthesis, mechanism and application in heavy metal ion adsorption and catalysis
文献类型：期刊论文
| 作者 | Li, Wei1,2; Xia, Fang2; Qu, Jin1; Li, Ping1; Chen, Dehong3; Chen, Zhe1; Yu, Yu1; Lu, Yu2; Caruso, Rachel A.2,3; Song, Weiguo1 |
| 刊名 | NANO RESEARCH
 |
| 出版日期 | 2014-06-01 |
| 卷号 | 7期号:6页码:903-916 |
| 关键词 | Wox-ethylenediamine Nanowires Synchrotron-radiation X-ray Diffraction Heavy Metal Water Treatment Catalysis |
| ISSN号 | 1998-0124 |
| DOI | 10.1007/s12274-014-0452-9 |
| 英文摘要 | Inorganic-organic hybrid WOx-ethylenediamine (WOx-EDA) nanowires have been produced by a simple, low-cost and high-yield solvothermal method. These WOx-EDA hybrid nanowires have unique lamellar mesostructures with an alternate stacking of an interconnected [WO6] octahedral layer and a monolayer of ethylenediamine molecules. This hybrid structure integrated the functionality of ethylenediamine with the stability of the WOx frameworks. In situ synchrotron-radiation X-ray diffraction is used to elucidate a possible formation mechanism of the hybrid WOx-EDA. The nanowire morphology, lamellar structure and abundant functional amino groups endow them with versatile abilities. For example, in heavy metal ion adsorption the WOx-EDA nanowires display exceptional adsorption capabilities of 925 mg.g(-1) for Pb2+ and 610 mg.g(-1) for UO22+. The nanowires also show outstanding stability and activity as a heterogeneous base catalyst in the Knoevenagel condensation reaction at room temperature. The catalyst can be recycled and reused for 20 cycles with nearly 100% yields. This study provides a new strategy to design inorganic-organic hybrid materials, and offers a multifunctional material that is a highly efficient adsorbent and sustainable catalyst. |
| 语种 | 英语 |
| WOS记录号 | WOS:000339892000012 |
| 出版者 | TSINGHUA UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/52085]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Song, Weiguo |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China 2.CSIRO Mat Sci & Engn, Clayton S South, Vic 3169, Australia 3.Univ Melbourne, Sch Chem, PFPC, Melbourne, Vic 3010, Australia |
| 推荐引用方式 GB/T 7714 | Li, Wei,Xia, Fang,Qu, Jin,et al. Versatile inorganic-organic hybrid WOx-ethylenediamine nanowires: Synthesis, mechanism and application in heavy metal ion adsorption and catalysis[J]. NANO RESEARCH,2014,7(6):903-916. |
| APA | Li, Wei.,Xia, Fang.,Qu, Jin.,Li, Ping.,Chen, Dehong.,...&Song, Weiguo.(2014).Versatile inorganic-organic hybrid WOx-ethylenediamine nanowires: Synthesis, mechanism and application in heavy metal ion adsorption and catalysis.NANO RESEARCH,7(6),903-916. |
| MLA | Li, Wei,et al."Versatile inorganic-organic hybrid WOx-ethylenediamine nanowires: Synthesis, mechanism and application in heavy metal ion adsorption and catalysis".NANO RESEARCH 7.6(2014):903-916. |
入库方式： OAI收割
来源：化学研究所
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